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Cobalt(II) chloride is an inorganic compound, a salt of cobalt and chlorine, with the formula CoCl 2.The compound forms several hydrates CoCl 2 ·n H 2 O, for n = 1, 2, 6, and 9. . Claims of the formation of tri- and tetrahydrates have not been confirmed
Cobalt(III) chloride or cobaltic chloride is an unstable and elusive compound of cobalt and chlorine with formula CoCl 3. In this compound, the cobalt atoms have a formal charge of +3. [1] The compound has been reported to exist in the gas phase at high temperatures, in equilibrium with cobalt(II) chloride and chlorine gas.
Hexaamminecobalt(III) chloride is the chemical compound with the formula [Co(NH 3) 6]Cl 3. It is the chloride salt of the coordination complex [Co(NH 3 ) 6 ] 3+ , which is considered an archetypal "Werner complex", named after the pioneer of coordination chemistry, Alfred Werner .
The salt is prepared with a two-step process starting with oxidizing a solution of cobalt chloride and ammonia. [1] [2] 2 CoCl 2 ·6H 2 O + 10 NH 3 + 2 HCl + H 2 O 2 → 2 [Co(NH 3) 5 (OH 2)]Cl 3 + 12 H 2 O. This intermediate is then heated to induce coordination of one of the outer sphere chloride ligands: [Co(NH 3) 5 (OH 2)]Cl 3 → [Co(NH 3 ...
trans-Dichlorobis(ethylenediamine)cobalt(III) chloride is a salt with the formula [CoCl 2 (en) 2]Cl (en = ethylenediamine). It is a green diamagnetic solid that is soluble in water. It is the monochloride salt of the cationic coordination complex [CoCl 2 (en) 2] +. One chloride ion in this salt readily undergoes ion exchange but the two other ...
An equilibrium constant is related to the standard Gibbs free energy change for the reaction = R is the gas constant and T is the absolute temperature. At 25 °C, ΔG ⊖ = (−5.708 kJ mol −1) ⋅ log β. Free energy is made up of an enthalpy term and an entropy term.
Many halides of cobalt(II) are known.e cobalt(II) fluoride (CoF 2) which is a pink solid, cobalt(II) chloride (CoCl 2) which is a blue solid, cobalt(II) bromide (CoBr 2) which is a green solid, and cobalt(II) iodide (CoI 2) which is a blue-black solid. In addition to the anhydrous forms, these cobalt halides also have hydrates.
Cis-dichlorobis(ethylenediamine)cobalt(III) chloride is obtained by heating a solution of trans-dichlorobis(ethylenediamine)cobalt(III) chloride, e.g. using a steam bath. The racemate can be resolved into two enantiomers (Λ and Δ) by the formation of the d-α-bromocamphor-π-sulfonate salt. The diastereomeric salts are separated by ...