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Acetophenone is formed as a byproduct of the cumene process, the industrial route for the synthesis of phenol and acetone.In the Hock rearrangement of isopropylbenzene hydroperoxide, migration of a methyl group rather than the phenyl group gives acetophenone and methanol as a result of an alternate rearrangement of the intermediate:
An example with modified reagents (sulfur, concentrated ammonium hydroxide and pyridine) is the conversion of acetophenone to 2-phenylacetamide and phenylacetic acid [5] The Willgerodt rearrangement using acetophenone
1-Phenylethylamine may be prepared by the reductive amination of acetophenone: [1] C 6 H 5 C(O)CH 3 + NH 3 + H 2 → C 6 H 5 CH(NH 2)CH 3 + H 2 O. The Leuckart reaction, using ammonium formate, is another method for this transformation. [2] L-malic acid is used to resolve 1-Phenylethylamine, a versatile resolving agent in its own right.
Chemical formula. C 8 H 7 Br O: Molar mass: 199.047 g·mol −1 Appearance ... It is prepared by bromination of acetophenone: [2] C 6 H 5 C(O)CH 3 + Br 2 → C 6 H 5 ...
Phenacyl chloride, also commonly known as chloroacetophenone, is a substituted acetophenone.It is a useful building block in organic chemistry.Apart from that, it has been historically used as a riot control agent, where it is designated CN. [5]
Acetanisole is an aromatic chemical compound with an aroma described as sweet, fruity, nutty, and similar to vanilla. In addition acetanisole can sometimes smell like butter or caramel. [ 3 ] Its chemical names are based on considering the structure as either an acetyl ( methyl - ketone ) analog of anisole .
The Bischler–Möhlau indole synthesis, also often referred to as the Bischler indole synthesis, [1] is a chemical reaction that forms a 2-aryl-indole from an α-bromo-acetophenone and excess aniline; it is named after August Bischler and Richard Möhlau [].
Phenylacetone, also known as phenyl-2-propanone, is an organic compound with the chemical formula C 6 H 5 CH 2 COCH 3. It is a colorless oil that is soluble in organic solvents. It is a mono-substituted benzene derivative, consisting of an acetone attached to a phenyl group. As such, its systematic IUPAC name is 1-phenyl-2-propanone.