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Diphenyl sulfide and its analogues can also be produced by coupling reactions using metal catalysts. [5] It can also be prepared by reduction of diphenyl sulfone. [6] Diphenyl sulfide is a product of the photodegradation of the fungicide edifenphos. [7] Diphenyl sulfide is a precursor to triaryl sulfonium salts, which are used as photoinitiators.
Diphenyl sulfone is an organosulfur compound with the formula (C 6 H 5) 2 SO 2.It is a white solid that is soluble in organic solvents.It is used as a high temperature solvent. Such high temperature solvents are useful for processing highly rigid polymers, e.g., PEEK, which only dissolve in very hot solve
Exceptions include bisphenol S, P, and M. "Bisphenol" is a common name; the letter following denotes the variant, which depends on the additional substituents. Bisphenol A is the most popular representative of the group, with millions of metric tons produced globally in the past decade, often simply called "bisphenol". [3] [4] [5]
Hydrogen peroxide can also be used as the oxidant. [2] Ph 2 S 2 is rarely prepared in the laboratory because it is inexpensive, and the precursor has a disagreeable odour. Like most organic disulfides, the C–S–S–C core of Ph 2 S 2 is non-planar with a dihedral angle approaching 85°. [3] Ball-and-stick model of diphenyl disulfide.
DCDPS is synthesized via sulfonation of chlorobenzene with sulfuric acid, often in the presence of various additives to optimize the formation of the 4,4′-isomer: . ClC 6 H 5 + SO 3 → (ClC 6 H 4) 2 SO 2 + H 2 O
BPA is used to form a number of flame retardants used in plastics. [61] Bromination of BPA forms tetrabromobisphenol A (TBBPA), which is mainly used as a reactive component of polymers, meaning that it is incorporated into the polymer backbone. It is used to prepare fire-resistant polycarbonates by replacing some bisphenol A
Long-term effects seem to include a slight excess of multiple myeloma and myeloid leukaemia, [19] as well as some developmental effects such as disturbed development of teeth [41] and excess of girls born to fathers who were exposed as children. [52] Several other long-term effects have been suspected, but the evidence is not very strong. [5]
4,6-Dimethyldibenzothiophene is an organosulfur compound with the formula (C 6 H 3 CH 3) 2 S.It is one of several dimethyl derivatives of benzothiophene.The compound is of particular interest as an organosulfur contaminant in petroleum that is recalcitrant.