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Thermodynamic heat pump cycles or refrigeration cycles are the conceptual and mathematical models for heat pump, air conditioning and refrigeration systems. [1] A heat pump is a mechanical system that transmits heat from one location (the "source") at a certain temperature to another location (the "sink" or "heat sink") at a higher temperature. [2]
Q H = W + Q C = heat exchanged with the hot reservoir. η = W / (Q C + Q H) = thermal efficiency of the cycle If the cycle moves in a clockwise sense, then it is a heat engine that outputs work; if the cycle moves in a counterclockwise sense, it is a heat pump that takes in work and moves heat Q H from the cold reservoir to the hot reservoir.
Thermodynamic heat pump cycles are the models for household heat pumps and refrigerators. There is no difference between the two except the purpose of the refrigerator is to cool a very small space while the household heat pump is intended to warm or cool a house. Both work by moving heat from a cold space to a warm space.
In general, heat pumps work most efficiently (that is, the heat output produced for a given energy input) when the difference between the heat source and the heat sink is small. When using a heat pump for space or water heating, therefore, the heat pump will be most efficient in mild conditions, and decline in efficiency on very cold days.
Higher COPs equate to higher efficiency, lower energy (power) consumption and thus lower operating costs. The COP usually exceeds 1, especially in heat pumps, because instead of just converting work to heat (which, if 100% efficient, would be a COP of 1), it pumps additional heat from a heat source to where the heat is required.
P-T Diagram showing the temperature gliding in binary heat pump. This behaviour increase the efficiency of ACHP Ammonia toxicity is the main drawback of ACHP. The main advantage with respect to compression heat pump is that the compression-absorption heat pumps allow the heat to be transfer with a temperature glide.
The main feature of thermodynamic diagrams is the equivalence between the area in the diagram and energy. When air changes pressure and temperature during a process and prescribes a closed curve within the diagram the area enclosed by this curve is proportional to the energy which has been gained or released by the air.
Temperature vs. heat load diagram of hot stream (H 2 O entering at 20 bar, 473.15 K, and 4 kg/s) and cold stream (R-11 entering at 18 bar, 303.15 K, and 5 kg/s) in a counter-flow heat exchanger. "Pinch" is the point of closest approach between the hot and cold streams in the T vs. H diagram.
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