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The amylose/amylopectin ratio, molecular weight and molecular fine structure influences the physicochemical properties as well as energy release of different types of starches, [28] which affects the number of calories people consume from food. Amylopectin is also sometimes used as a workout supplement due to this caloric density and a ...
Structure of the amylose molecule Structure of the amylopectin molecule Starch or amylum is a polymeric carbohydrate consisting of numerous glucose units joined by glycosidic bonds . This polysaccharide is produced by most green plants for energy storage.
Amylose A is a parallel double-helix of linear chains of glucose. Amylose is made up of α(1→4) bound glucose molecules. The carbon atoms on glucose are numbered, starting at the aldehyde (C=O) carbon, so, in amylose, the 1-carbon on one glucose molecule is linked to the 4-carbon on the next glucose molecule (α(1→4) bonds). [3]
Thus, amylopectin, waxy starches alone, cannot be correlated to good digestibility. Sandsted suggests that digestibility could lie more in the structure of starch granule, in differences in bonding of the starch molecules and in possible anomalous linkages between the molecules. [citation needed]
It is made up of a mixture of amylose (15–20%) and amylopectin (80–85%). Amylose consists of a linear chain of several hundred glucose molecules, and Amylopectin is a branched molecule made of several thousand glucose units (every chain of 24–30 glucose units is one unit of Amylopectin). Starches are insoluble in water.
During cooling, starch molecules gradually aggregate to form a gel. The following molecular associations can occur: amylose-amylose, amylose-amylopectin, and amylopectin-amylopectin. A mild association amongst chains come together with water still embedded in the molecule network.
The glucose chains can reassociate into short crystalline structures, which typically involves rapid recrystallization of amylose molecules followed by a slow recrystallization of amylopectin molecules in a process called retrogradation. [40] Plants produce starch with different types of structure and shape characteristics which may affect ...
Cyclodextrins have toroidal structures formed by 6–8 glucose residues. Amylodextrin is a linear dextrin or short chained amylose (DP 20-30) that can be produced by enzymatic hydrolysis of the alpha-1,6 glycosidic bonds or debranching amylopectin. Amylodextrin colors blue with iodine.