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The lanthanide contraction is the greater-than-expected decrease in atomic radii and ionic radii of the elements in the lanthanide series, from left to right. It is caused by the poor shielding effect of nuclear charge by the 4f electrons along with the expected periodic trend of increasing electronegativity and nuclear charge on moving from left to right.
The lanthanide contraction, i.e. the reduction in size of the Ln 3+ ion from La 3+ (103 pm) to Lu 3+ (86.1 pm), is often explained by the poor shielding of the 5s and 5p electrons by the 4f electrons. [18] Lanthanide oxides: clockwise from top center: praseodymium, cerium, lanthanum, neodymium, samarium and gadolinium.
The lanthanide contraction only partially accounts for this anomaly. [11] Because the 6s 2 orbital is contracted by relativistic effects and may therefore only weakly contribute to any chemical bonding, Hg–Hg bonding must be mostly the result of van der Waals forces. [11] [13] [14] Mercury gas is mostly monatomic, Hg(g).
The reductions in atomic size due to the interjection of the d- and f-blocks are referred to as, respectively, the 'scandide' or 'd-block contraction', [n 3] and the 'lanthanide contraction'. [13] Relativistic effects also "increase the binding energy", and hence ionisation energy, of the electrons in "the 6s shell in gold and mercury, and the ...
The effect of the lanthanide contraction can be observed in the REE behaviour both in a CHARAC-type geochemical system (CHArge-and-RAdius-Controlled [40]) where elements with similar charge and radius should show coherent geochemical behaviour, and in non-CHARAC systems, such as aqueous solutions, where the electron structure is also an ...
This is an effect of the lanthanide contraction: the expected increase of atomic radius from the 4d to the 5d elements is wiped out by the insertion of the 4f elements before. Titanium, being smaller, is distinct from these two: its oxide is less basic than those of zirconium and hafnium, and its aqueous chemistry is more hydrolyzed. [ 28 ]
The trivalent lanthanide ions decrease steadily in size from lanthanum to lutetium, an effect known as the lanthanide contraction. [31] From lanthanum to dysprosium , the coordination number is maintained at 9 with a tricapped trigonal prismatic structure, although starting from samarium the capping water molecules are no longer equally ...
Due to the effects of the lanthanide contraction, yttrium and lutetium are very similar in properties. Yttrium and lutetium have essentially the chemistry of the heavy lanthanides, but scandium shows several differences due to its small size. This is a similar pattern to those of the early transition metal groups, where the lightest element is ...