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The alkali–carbonate reaction is an alteration process first suspected in the 1950s in Canada for the degradation of concrete containing dolomite aggregates. [1] [2]Alkali from the cement might react with the dolomite crystals present in the aggregate inducing the production of brucite, (MgOH) 2, and calcite (CaCO 3).
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
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Thermodynamic datafile for MgCl 2 (c,l,g) from FREED. Some values have truncated significant figures for display purposes. The explanation for the values is shown below. Row 1. Molar mass of species, density at 298.15 K, ΔH° form 298.15, S° 298.15. and the upper temperature limit for the file. Row 2. Number of C p equations required. Here ...
Download as PDF; Printable version; In other projects ... Units of solubility are given in grams of substance per 100 millilitres of water (g/(100 mL)), unless shown ...
Water phase diagram. Y-axis=Pressure in pascals (10 n). X-axis=Temperature in kelvins. S=Solid; L=Liquid; V=Vapour, CP=Critical Point, TP=Triple Point: Date: September 2006: Source: Own work: Author: Eurico Zimbres: Permission (Reusing this file) Free for all use: Other versions: phase diagram with description but without units of measurement
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Carbonatation is a slow process that occurs in concrete where lime (CaO, or Ca(OH) 2 ) in the cement reacts with carbon dioxide (CO 2) from the air and forms calcium carbonate. The water in the pores of Portland cement concrete is normally alkaline with a pH in the range of 12.5 to 13.5.