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The simplest aryl group is phenyl, which is made up of a benzene ring with one of its hydrogen atom replaced by some substituent, and has the molecular formula C 6 H 5 −. Note that a phenyl group is not the same as a benzyl group, the latter consisting of a phenyl group attached to a methyl group and a molecular formula of C 6 H 5 CH 2 −. [2]
In organic chemistry, the phenyl group, or phenyl ring, is a cyclic group of atoms with the formula C6H5, and is often represented by the symbol Ph (archaically φ) or Ø. The phenyl group is closely related to benzene and can be viewed as a benzene ring, minus a hydrogen, which may be replaced by some other element or compound to serve as a ...
Benzyl is not to be confused with phenyl with the formula C 6 H 5. The term benzylic is used to describe the position of the first carbon bonded to a benzene or other aromatic ring. For example, (C 6 H 5)(CH 3) 2 C + is referred to as a "benzylic" carbocation. The benzyl free radical has the formula C 6 H 5 CH 2 •.
An ethoxy group (CH 3 CH 2 O−) is found in the organic compound ethyl phenyl ether (C 6 H 5 OCH 2 CH 3, also known as ethoxybenzene). Related to alkoxy groups are aryloxy groups, which have an aryl group singularly bonded to oxygen such as the phenoxy group (C 6 H 5 O−). An alkoxy or aryloxy group bonded to an alkyl or aryl (R−O−R') is ...
As such, an Ullmann condensation can be employed: an aryl halide is able to react with phenol (or its derivatives) to form a bis-aryl ether in the presence of a copper-based catalyst, such as copper(II) oxide. [7] An Ullmann condensation between p-methylphenolate and bromobenzene in the presence of a copper catalyst to form 4-methyl-1 ...
The acidity of the hydroxyl group in phenols is commonly intermediate between that of aliphatic alcohols and carboxylic acids (their pK a is usually between 10 and 12). Deprotonation of a phenol forms a corresponding negative phenolate ion or phenoxide ion , and the corresponding salts are called phenolates or phenoxides ( aryloxides according ...
[15] [16] In particular the Krafft point of the high 2-phenyl product (i.e. the least branched isomer) remains below 0 °C up to 25% LAS whereas the low 2-phenyl cloud point is ~15 °C. [17] This behavior is often exploited by producers to create either clear or cloudy products.
The acyls are between the hydrocarbyls and the carboxylic acids. The hydrocarbyl group names that end in -yl are not acyl groups, but alkyl groups derived from alkanes ( methyl , ethyl , propyl , butyl ), alkenyl groups derived from alkenes ( propenyl , butenyl), or aryl groups ( benzyl ).