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1,4-Dichlorobenzene (1,4-DCB, p-DCB, or para-dichlorobenzene, sometimes abbreviated as PDCB or para) is an aryl chloride and isomer of dichlorobenzene with the formula C 6 H 4 Cl 2. This colorless solid has a strong odor. The molecule consists of a benzene ring with two chlorine atoms (replacing hydrogen atoms) on opposing sites of the ring.
1,2-Dichlorobenzene or ortho-dichlorobenzene; 1,3-Dichlorobenzene or meta-dichlorobenzene; 1,4-Dichlorobenzene or para-dichlorobenzene. All three isomers are colorless chlorobenzenes with the formula C 6 H 4 Cl 2. They differ structurally based on where the two chlorine atoms are attached to the ring.
Both naphthalene and 1,4-dichlorobenzene undergo sublimation, meaning that they transition from a solid state directly into a gas; this gas is toxic to moths and moth larvae. [ 1 ] Due to the health risks of 1,4-dichlorobenzene, and flammability of naphthalene, other substances like camphor are sometimes used.
1,4-Dichlorobutane is a chloroalkane with the molecular formula (CH 2 CH 2 Cl) 2. It is one of several structural isomers of dichlorobutane. They are all colorless liquids of low flammabiltity and of interest for specialized synthetic uses.
The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet for this chemical from a reliable source and follow its directions. An external MSDS is available here.
Materials may react violently with water or form peroxides upon exposure to air (e.g., potassium, sodium). 1. Materials that are normally stable but can become unstable (self-react) at high temperatures and pressures. Materials may react non-violently with water or undergo hazardous polymerization in the absence of inhibitors (e.g., propene). 0.
The PPS (polyphenylene sulfide) polymer is formed by reaction of sodium sulfide with 1,4-dichlorobenzene: n ClC 6 H 4 Cl + n Na 2 S → [C 6 H 4 S] n + 2n NaCl Hill and Edmonds, developers of PPS. The process for commercially producing this material was initially developed by Dr. H. Wayne Hill Jr. and James T. Edmonds at Phillips Petroleum. [7]
The LD50 (oral, rats) is 756 mg/kg. Animal studies have shown that 1,2,4-trichlorobenzene affects the liver and kidney, and is possibly a teratogen. [4] There is no regulated occupational exposure limit for chemical exposure, but the National Institute for Occupational Safety and Health recommends no greater exposure than 5 ppm, over an 8-hour workday.