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Group theory has three main historical sources: number theory, the theory of algebraic equations, and geometry.The number-theoretic strand was begun by Leonhard Euler, and developed by Gauss's work on modular arithmetic and additive and multiplicative groups related to quadratic fields.
The rule arises because in a centrosymmetric point group, IR active modes, which must transform according to the same irreducible representation generated by one of the components of the dipole moment vector (x, y or z), must be of ungerade (u) symmetry, i.e. their character under inversion is -1, while Raman active modes, which transform ...
Various physical systems, such as crystals and the hydrogen atom, may be modelled by symmetry groups. Thus group theory and the closely related representation theory have many important applications in physics, chemistry, and materials science. Group theory is also central to public key cryptography.
Molecular symmetry is a fundamental concept in chemistry, as it can be used to predict or explain many of a molecule's chemical properties, such as whether or not it has a dipole moment, as well as its allowed spectroscopic transitions. To do this it is necessary to use group theory.
In mathematics, specifically in group theory, the direct product is an operation that takes two groups G and H and constructs a new group, usually denoted G × H.This operation is the group-theoretic analogue of the Cartesian product of sets and is one of several important notions of direct product in mathematics.
The semisimple Lie groups have a deep theory, building on the compact case. The complementary solvable Lie groups cannot be classified in the same way. The general theory for Lie groups deals with semidirect products of the two types, by means of general results called Mackey theory, which is a generalization of Wigner's classification methods.
A presentation of a group determines a geometry, in the sense of geometric group theory: one has the Cayley graph, which has a metric, called the word metric. These are also two resulting orders, the weak order and the Bruhat order, and corresponding Hasse diagrams. An important example is in the Coxeter groups.
The simplest form of a group-contribution method is the determination of a component property by summing up the group contributions : [] = +.This simple form assumes that the property (normal boiling point in the example) is strictly linearly dependent on the number of groups, and additionally no interaction between groups and molecules are assumed.