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Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials. Circular birefringence and circular dichroism are the manifestations of optical activity.
Specific rotation is an intensive property, distinguishing it from the more general phenomenon of optical rotation. As such, the observed rotation (α) of a sample of a compound can be used to quantify the enantiomeric excess of that compound, provided that the specific rotation ([α]) for the enantiopure compound is known.
A polarimeter [1] is a scientific instrument used to measure optical rotation: the angle of rotation caused by passing linearly polarized light through an optically active substance. [ 2 ] Some chemical substances are optically active, and linearly polarized (uni-directional) light will rotate either to the left (counter-clockwise) or right ...
Faraday rotation is an important tool in astronomy for the measurement of magnetic fields, which can be estimated from rotation measures given a knowledge of the electron number density. [14] In the case of radio pulsars , the dispersion caused by these electrons results in a time delay between pulses received at different wavelengths, which ...
Polarimetry is the measurement and interpretation of the polarization of transverse waves, most notably electromagnetic waves, such as radio or light waves. Typically polarimetry is done on electromagnetic waves that have traveled through or have been reflected , refracted or diffracted by some material in order to characterize that object.
Birefringence and other polarization-based optical effects (such as optical rotation and linear or circular dichroism) can be observed by measuring any change in the polarization of light passing through the material. These measurements are known as polarimetry.
Optical rotatory dispersion is the variation in optical rotation with wavelength. ORD and CD spectra both derive from the interaction of polarized (circularly or linearly) light with chiral molecules and are directly related: each can be derived from the other using the Kramers-Kronig transform. Measurements of ORD and CD give essentially the ...
When the magnetization vector is perpendicular to the reflection surface and parallel to the plane of incidence, the effect is called the polar Kerr effect.To simplify the analysis, and because the other two configurations have vanishing Kerr rotation at normal incidence, near normal incidence is usually employed when doing experiments in the polar geometry.
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