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  2. Molecular symmetry - Wikipedia

    en.wikipedia.org/wiki/Molecular_symmetry

    In a symmetry group, the group elements are the symmetry operations (not the symmetry elements), and the binary combination consists of applying first one symmetry operation and then the other. An example is the sequence of a C 4 rotation about the z-axis and a reflection in the xy-plane, denoted σ(xy) C 4 .

  3. Point groups in three dimensions - Wikipedia

    en.wikipedia.org/wiki/Point_groups_in_three...

    D nh is the symmetry group for a "regular" n-gonal prism and also for a "regular" n-gonal bipyramid. D nd is the symmetry group for a "regular" n-gonal antiprism, and also for a "regular" n-gonal trapezohedron. D n is the symmetry group of a partially rotated ("twisted") prism. The groups D 2 and D 2h are noteworthy in that there is no special ...

  4. Symmetry group - Wikipedia

    en.wikipedia.org/wiki/Symmetry_group

    In group theory, the symmetry group of a geometric object is the group of all transformations under which the object is invariant, endowed with the group operation of composition. Such a transformation is an invertible mapping of the ambient space which takes the object to itself, and which preserves all the relevant structure of the object.

  5. List of character tables for chemically important 3D point groups

    en.wikipedia.org/wiki/List_of_character_tables...

    For each non-linear group, the tables give the most standard notation of the finite group isomorphic to the point group, followed by the order of the group (number of invariant symmetry operations). The finite group notation used is: Z n: cyclic group of order n, D n: dihedral group isomorphic to the symmetry group of an n–sided regular ...

  6. Octahedral molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Octahedral_molecular_geometry

    In chemistry, octahedral molecular geometry, also called square bipyramidal, [1] describes the shape of compounds with six atoms or groups of atoms or ligands symmetrically arranged around a central atom, defining the vertices of an octahedron. The octahedron has eight faces, hence the prefix octa.

  7. Square pyramidal molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Square_pyramidal_molecular...

    The point group symmetry involved is of type C 4v. The geometry is common for certain main group compounds that have a stereochemically-active lone pair, as described by VSEPR theory. Certain compounds crystallize in both the trigonal bipyramidal and the square pyramidal structures, notably [Ni(CN) 5] 3−. [1]

  8. Tetrahedral molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Tetrahedral_molecular_geometry

    In a tetrahedral molecular geometry, a central atom is located at the center with four substituents that are located at the corners of a tetrahedron. The bond angles are arccos (− ⁠ 1 / 3 ⁠ ) = 109.4712206...° ≈ 109.5° when all four substituents are the same, as in methane ( CH 4 ) [ 1 ] [ 2 ] as well as its heavier analogues .

  9. Symmetry element - Wikipedia

    en.wikipedia.org/wiki/Symmetry_element

    The elements of this symmetry group should not be confused with the "symmetry element" itself. Loosely, a symmetry element is the geometric set of fixed points of a symmetry operation. For example, for rotation about an axis, the points on the axis do not move and in a reflection the points that remain unchanged make up a plane of symmetry.