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  2. Halogen - Wikipedia

    en.wikipedia.org/wiki/Halogen

    The chemical reactivity of halogen atoms depends on both their point of attachment to the lead and the nature of the halogen. Aromatic halogen groups are far less reactive than aliphatic halogen groups, which can exhibit considerable chemical reactivity. For aliphatic carbon-halogen bonds, the C-F bond is the strongest and usually less ...

  3. Halogenation - Wikipedia

    en.wikipedia.org/wiki/Halogenation

    In chemistry, halogenation is a chemical reaction which introduces one or more halogens into a chemical compound. Halide-containing compounds are pervasive, making this type of transformation important, e.g. in the production of polymers, drugs. [1] This kind of conversion is in fact so common that a comprehensive overview is challenging.

  4. Free-radical halogenation - Wikipedia

    en.wikipedia.org/wiki/Free-radical_halogenation

    In organic chemistry, free-radical halogenation is a type of halogenation. This chemical reaction is typical of alkanes and alkyl-substituted aromatics under application of UV light. The reaction is used for the industrial synthesis of chloroform (CHCl 3), dichloromethane (CH 2 Cl 2), and hexachlorobutadiene. It proceeds by a free-radical chain ...

  5. Electrophilic halogenation - Wikipedia

    en.wikipedia.org/wiki/Electrophilic_halogenation

    Halogenation of benzene where X is the halogen, catalyst represents the catalyst (if needed) and HX represents the protonated base. A few types of aromatic compounds, such as phenol, will react without a catalyst, but for typical benzene derivatives with less reactive substrates, a Lewis acid is required as a catalyst.

  6. Hydrohalogenation - Wikipedia

    en.wikipedia.org/wiki/Hydrohalogenation

    A hydrohalogenation reaction is the electrophilic addition of hydrogen halides like hydrogen chloride or hydrogen bromide to alkenes to yield the corresponding haloalkanes. [ 1 ] [ 2 ] [ 3 ] If the two carbon atoms at the double bond are linked to a different number of hydrogen atoms, the halogen is found preferentially at the carbon with fewer ...

  7. Halogen addition reaction - Wikipedia

    en.wikipedia.org/wiki/Halogen_addition_reaction

    A halogen addition reaction is a simple organic reaction where a halogen molecule is added to the carbon–carbon double bond of an alkene functional group. [1] The general chemical formula of the halogen addition reaction is: C=C + X 2 → X−C−C−X (X represents the halogens bromine or chlorine, and in this case, a solvent could be CH 2 ...

  8. Dehalogenation - Wikipedia

    en.wikipedia.org/wiki/Dehalogenation

    In organic chemistry, dehalogenation is a set of chemical reactions that involve the cleavage of carbon-halogen bonds; as such, it is the inverse reaction of halogenation. Dehalogenations come in many varieties, including defluorination (removal of fluorine ), dechlorination (removal of chlorine ), debromination (removal of bromine ), and ...

  9. Pseudohalogen - Wikipedia

    en.wikipedia.org/wiki/Pseudohalogen

    Examples of non-symmetrical pseudohalogen compounds (pseudohalogen halides Ps−X, where Ps is a pseudohalogen and X is a halogen, or interpseudohalogens Ps 1 −Ps 2, where Ps 1 and Ps 2 are two different pseudohalogens), analogous to the binary interhalogen compounds, are cyanogen halides like cyanogen chloride (Cl−CN), cyanogen bromide (Br ...