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Viewing the lanthanides from left to right in the periodic table, the seven 4f atomic orbitals become progressively more filled (see above and Periodic table § Electron configuration table). The electronic configuration of most neutral gas-phase lanthanide atoms is [Xe]6s 2 4f n , where n is 56 less than the atomic number Z .
The lanthanides become harder as the series is traversed: as expected, lanthanum is a soft metal. Lanthanum has a relatively high resistivity of 615 nΩm at room temperature; in comparison, the value for the good conductor aluminium is only 26.50 nΩm. [28] [29] Lanthanum is the least volatile of the lanthanides. [30]
The ionic radii of the lanthanides decrease from 103 pm (La 3+) to 86 pm (Lu 3+) in the lanthanide series, electrons are added to the 4f shell.This first f shell is inside the full 5s and 5p shells (as well as the 6s shell in the neutral atom); the 4f shell is well-localized near the atomic nucleus and has little effect on chemical bonding.
Praseodymium is the third member of the lanthanide series, and a member of the rare-earth metals. In the periodic table, it appears between the lanthanides cerium to its left and neodymium to its right, and above the actinide protactinium. It is a ductile metal with a hardness comparable to that of silver. [11]
Electron configuration 4f 1 5d 1 6s 2 [3] ... Cerium is the second element in the lanthanide series, ... This effect is overwhelmed when the atom is positively ...
Neodymium is the fourth member of the lanthanide series. In the periodic table, it appears between the lanthanides praseodymium to its left and the radioactive element promethium to its right, and above the actinide uranium. Its 60 electrons are arranged in the configuration [Xe]4f 4 6s 2, of which the six 4f and 6s electrons are valence.
This is due to the closed-shell electron configuration of ytterbium ([Xe] 4f 14 6s 2), which causes only the two 6s electrons to be available for metallic bonding (in contrast to the other lanthanides where three electrons are available) and increases ytterbium's metallic radius.
This page shows the electron configurations of the neutral gaseous atoms in their ground states. For each atom the subshells are given first in concise form, then with all subshells written out, followed by the number of electrons per shell. For phosphorus (element 15) as an example, the concise form is [Ne] 3s 2 3p 3.