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Scandium(III) oxide or scandia is a inorganic compound with formula Sc 2 O 3.It is one of several oxides of rare earth elements with a high melting point.It is used in the preparation of other scandium compounds as well as in high-temperature systems (for its resistance to heat and thermal shock), electronic ceramics, and glass composition (as a helper material).
In all four halides, the scandium is 6-coordinated. They can be prepared by reacting scandium oxide or scandium hydroxide with the corresponding acid: [3] Sc(OH) 3 + 3 HX → ScX 3 + 3 H 2 O. The halides are Lewis acids; for example, ScF 3 dissolves in a solution containing excess fluoride ion to form [ScF 6] 3−. The coordination number 6 is ...
Scandium has been proposed for use in solid oxide fuel cells (SOFCs) as a dopant in the electrolyte material, typically zirconia (ZrO₂). [72] Scandium oxide (Sc₂O₃) is one of several possible additives to enhance the ionic conductivity of the zirconia, improving the overall thermal stability, performance and efficiency of the fuel cell. [73]
Scandium(III) hydroxide is an inorganic compound with the chemical formula Sc(OH) 3, the trivalent hydroxide of scandium. It is an amphoteric compound. [2] It is slightly soluble in water, and its saturated solution (pH = 7.85) contains Sc(OH) 3 and a small amount of Sc(OH) + 2. The solubility of scandium(III) hydroxide in water is 0.0279 mol/L.
Scandium oxide is amphoteric; lutetium oxide is more basic (although it can with difficulty be made to display some acidic properties), and yttrium oxide is more basic still. [58] Salts with strong acids of these metals are soluble, whereas those with weak acids (e.g. fluorides, phosphates, oxalates) are sparingly soluble or insoluble. [53]
Kangite is an exceedingly rare scandium mineral, a natural form of impure scandium oxide (Sc 2 O 3), with the formula (Sc,Ti,Al,Zr,Mg,Ca, ) 2 O 3. It crystallizes in the cubic crystal system diploidal class. [1] In terms of chemistry it scandium-analogue of tistarite. Both kangite and tistarite were discovered in the Allende meteorite. [2] [1 ...
Scandium triflate is used as a reagent in organic chemistry as a Lewis acid. [1] Compared to other Lewis acids, this reagent is stable towards water and can often be used in organic reactions as a true catalyst rather than one used in stoichiometric amounts. The compound is prepared by reaction of scandium oxide with trifluoromethanesulfonic acid.
Scandium compounds are compounds that contain the chemical element scandium Subcategories. This category has the following 2 subcategories, out of 2 total ...