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The reagent is an alkaline solution of potassium permanganate. Reaction with double or triple bonds (R 2 C=CR 2 or R−C≡C−R) causes the color to fade from purplish-pink to brown. Aldehydes and formic acid (and formates) also give a positive test. [43] The test is antiquated. Baeyer's reagent reaction
Substance Formula 0 °C 10 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C Barium acetate: Ba(C 2 H 3 O 2) 2: 58.8: 62: 72: 75: 78.5: 77: 75
A solution of potassium hypomanganate is produced: by two-electron reduction of potassium permanganate with excess potassium sulfite; [5] [6] MnO − 4 + SO 2− 3 + H 2 O → MnO 3− 4 + SO 2− 4 + 2 H + by the single-electron reduction of potassium manganate with hydrogen peroxide in 10 M potassium hydroxide solution; [7]
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In a strongly basic or alkaline solution, permanganate(VII) is reduced to the green manganate ion, MnO 2− 4 with an oxidation state of +6. MnO − 4 + e − → MnO 2− 4. In a neutral solution, however, it gets reduced to the brown manganese dioxide MnO 2 with an oxidation state of +4. 2 H 2 O + MnO − 4 + 3 e − → MnO 2 + 4 OH −
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Potassium permanganate, KMnO 4, is a widely used, versatile and powerful oxidising agent. Permanganic acid solutions are unstable, and gradually decompose into manganese dioxide, oxygen, and water, with initially formed manganese dioxide catalyzing further decomposition. [6] Decomposition is accelerated by heat, light, and acids.
Potassium manganate is the inorganic compound with the formula K 2 MnO 4. This green-colored salt is an intermediate in the industrial synthesis of potassium permanganate (KMnO 4), a common chemical. [1] Occasionally, potassium manganate and potassium permanganate are confused, but each compound's properties are distinct.