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Manganese(II) acetate are chemical compounds with the formula Mn(CH 3 CO 2) 2 ·(H 2 O)n where n = 0, 2, 4. These materials are white or pale pink solids.
Although manganese(III) triacetate has not been reported, salts of basic manganese(III) acetate are well characterized. Basic manganese acetate adopts the structure reminiscent of those of basic chromium acetate and basic iron acetate. The formula is [Mn 3 O(O 2 CCH 3) 6 L n]X where L is a ligand and X is an anion. The salt [Mn 3 O(O 2 CCH 3) 6 ...
Manganese acetate can refer to: Manganese(II) acetate; Manganese(III) acetate This page was last edited on 12 March 2021, at 07:07 (UTC). Text is available under the ...
Mn(acac) 3 has been prepared by the comproportionation of the manganese(II) compound Mn(acac) 2 with potassium permanganate in the presence of additional acetylacetone. [12] Alternatively the direct reaction of acetylacetone with potassium permanganate. [13] In terms of electronic structure, Mn(acac) 3 is high spin.
Manganese-mediated coupling reactions are radical coupling reactions between enolizable carbonyl compounds and unsaturated compounds initiated by a manganese(III) salt, typically manganese(III) acetate. Copper(II) acetate is sometimes used as a co-oxidant to assist in the oxidation of intermediate radicals to carbocations.
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Manganese(III) acetate is an oxidant useful in organic synthesis. Solid compounds of manganese(III) are characterized by its strong purple-red color and a preference for distorted octahedral coordination resulting from the Jahn-Teller effect .
Jacobsen's catalyst is the common name for N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride, a coordination compound of manganese and a salen-type ligand. It is used as an asymmetric catalyst in the Jacobsen epoxidation , which is renowned for its ability to enantioselectively transform prochiral alkenes ...