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  2. Structural isomer - Wikipedia

    en.wikipedia.org/wiki/Structural_isomer

    Functional isomers are structural isomers which have different functional groups, resulting in significantly different chemical and physical properties. [ 11 ] An example is the pair propanal H 3 C–CH 2 –C(=O)-H and acetone H 3 C–C(=O)–CH 3 : the first has a –C(=O)H functional group, which makes it an aldehyde , whereas the second has ...

  3. Isomer - Wikipedia

    en.wikipedia.org/wiki/Isomer

    Isomers do not necessarily share similar chemical or physical properties. Two main forms of isomerism are structural (or constitutional) isomerism, in which bonds between the atoms differ; and stereoisomerism (or spatial isomerism), in which the bonds are the same but the relative positions of the atoms differ. Isomeric relationships form a ...

  4. Octane - Wikipedia

    en.wikipedia.org/wiki/Octane

    Octane has many structural isomers that differ by the location of branching in the carbon chain. One of these isomers, 2,2,4-trimethylpentane (commonly called iso-octane), is used as one of the standard values in the octane rating scale. Octane is a component of gasoline and petroleum.

  5. Stereochemistry - Wikipedia

    en.wikipedia.org/wiki/Stereochemistry

    Stereochemistry, a subdiscipline of chemistry, studies the spatial arrangement of atoms that form the structure of molecules and their manipulation. [1] The study of stereochemistry focuses on the relationships between stereoisomers, which are defined as having the same molecular formula and sequence of bonded atoms (constitution) but differing in the geometric positioning of the atoms in space.

  6. Stereoisomerism - Wikipedia

    en.wikipedia.org/wiki/Stereoisomerism

    Since chlorine has a larger atomic number than hydrogen, it is the highest-priority group. [9] Using this notation to name the above pictured molecules, molecule I is (Z)-1,2-dichloroethene and molecule II is (E)-1,2-dichloroethene. It is not the case that Z and cis, or E and trans, are always interchangeable. Consider the following ...

  7. Rotamer - Wikipedia

    en.wikipedia.org/wiki/Rotamer

    The question of whether steric hindrance is responsible for the eclipsed energy maximum is a topic of debate to this day. One alternative to the steric hindrance explanation is based on hyperconjugation as analyzed within the Natural Bond Orbital framework.

  8. Self-determination - Wikipedia

    en.wikipedia.org/wiki/Self-determination

    In contrast, Rosa Luxemburg called a "right of nations to self-determination", valid for all countries and all times, "nothing more than a metaphysical cliché" that offers no "practical solution of nationality problems" and argued that the very concept of the nation as an "homogenous social and political entity" was derived from bourgeois ...

  9. Isomerase - Wikipedia

    en.wikipedia.org/wiki/Isomerase

    Isomers themselves exist in many varieties but can generally be classified as structural isomers or stereoisomers. Structural isomers have a different ordering of bonds and/or different bond connectivity from one another, as in the case of hexane and its four other isomeric forms ( 2-methylpentane , 3-methylpentane , 2,2-dimethylbutane , and 2 ...