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For technetium-98 and heavier isotopes, the primary mode is beta emission (the emission of an electron or positron), producing ruthenium (Z = 44), with the exception that technetium-100 can decay both by beta emission and electron capture. [59] [60] Technetium also has numerous nuclear isomers, which are isotopes with one or more excited nucleons.
Both of these decay modes rearrange the nucleons without transmuting the technetium into another element. 99m Tc decays mainly by gamma emission, slightly less than 88% of the time. ( 99m Tc → 99 Tc + γ) About 98.6% of these gamma decays result in 140.5 keV gamma rays and the remaining 1.4% are to gammas of a slightly higher energy at 142.6 keV.
The metastable technetium-99m (99m Tc) is a short-lived (half-life about 6 hours) nuclear isomer used in nuclear medicine, produced from molybdenum-99. It decays by isomeric transition to technetium-99, a desirable characteristic, since the very long half-life and type of decay of technetium-99 imposes little further radiation burden on the body.
Technetium forms the simple carbon insertion phases with low carbon content up to 17 at.% of C when reacted with grphite [16] or by thermolisys of organic pertechnetates. [17] Tc is considered to be the last d-element to have some low but notable affinity to carbon.
Unstable isotopes decay through various radioactive decay pathways, most commonly alpha decay, beta decay, or electron capture. Many rare types of decay, such as spontaneous fission or cluster decay, are known. (See Radioactive decay for details.) [citation needed] Of the first 82 elements in the periodic table, 80 have isotopes considered to ...
Beta decay of fission products of mass 95–98 stops at the stable isotopes of molybdenum of those masses and does not reach technetium. For mass 100 and greater, the technetium isotopes of those masses are very short-lived and quickly beta decay to isotopes of ruthenium. Therefore, the technetium in spent nuclear fuel is practically all 99 Tc.
The decay scheme of a radioactive substance is a graphical presentation of all the transitions occurring in a decay, and of their relationships. Examples are shown below. It is useful to think of the decay scheme as placed in a coordinate system, where the vertical axis is energy, increasing from bottom to top, and the horizontal axis is the proton number, increasing from left to right.
The longer-lived isotope, technetium-95m with a half-life of 61 days, is used as a radioactive tracer to study the movement of technetium in the environment and in plant and animal systems. [ 116 ] Technetium-99 decays almost entirely by beta decay, emitting beta particles with consistent low energies and no accompanying gamma rays.