Search results
Results from the WOW.Com Content Network
Rotational energies are quantized. For a diatomic molecule like CO or HCl, or a linear polyatomic molecule like OCS in its ground vibrational state, the allowed rotational energies in the rigid rotor approximation are = = (+) = (+). J is the quantum number for total rotational angular momentum and takes all integer values starting at zero, i.e., =,,, …, = is the rotational constant, and is ...
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
In astronomy, the rotation period or spin period [1] of a celestial object (e.g., star, planet, moon, asteroid) has two definitions. The first one corresponds to the sidereal rotation period (or sidereal day), i.e., the time that the object takes to complete a full rotation around its axis relative to the background stars (inertial space).
In chemistry, specific rotation ([α]) is a property of a chiral chemical compound. [ 1 ] : 244 It is defined as the change in orientation of monochromatic plane-polarized light , per unit distance–concentration product, as the light passes through a sample of a compound in solution.
The rotation rate of the Earth (Ω = 7.2921 × 10 −5 rad/s) can be calculated as 2π / T radians per second, where T is the rotation period of the Earth which is one sidereal day (23 h 56 min 4.1 s). [2] In the midlatitudes, the typical value for is about 10 −4 rad/s.
Dextrorotation and laevorotation (also spelled levorotation) [1] [2] in chemistry and physics are the optical rotation of plane-polarized light.From the point of view of the observer, dextrorotation refers to clockwise or right-handed rotation, and laevorotation refers to counterclockwise or left-handed rotation.
An example is the calculation of the rotational kinetic energy of the Earth. As the Earth has a sidereal rotation period of 23.93 hours, it has an angular velocity of 7.29 × 10 −5 rad·s −1. [2] The Earth has a moment of inertia, I = 8.04 × 10 37 kg·m 2. [3] Therefore, it has a rotational kinetic energy of 2.14 × 10 29 J.
This is especially useful if μ is assumed to be known, as then n can be used to calculate a, and likewise for specifying a. This can allow one less element to specified. Orbital period can be found from n given the fact that the mean motion can be described as a frequency (number of orbits per unit time), which is the inverse of period.