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Nickel nitrate is the inorganic compound Ni(NO 3) 2 or any hydrate thereof. In the hexahydrate, the nitrate anions are not bonded to nickel. Other hydrates have also been reported: Ni(NO 3) 2. 9H 2 O, Ni(NO 3) 2. 4H 2 O, and Ni(NO 3) 2. 2H 2 O. [3] It is prepared by the reaction of nickel oxide with nitric acid: NiO + 2 HNO 3 + 5 H 2 O → Ni ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
[Ni(NH 3) 6] 2+, like all octahedral nickel(II) complexes, is paramagnetic with two unpaired electrons localized on each Ni center. [Ni(NH 3) 6]Cl 2 is prepared by treating aqueous nickel(II) chloride with ammonia. It is useful as a molecular source of anhydrous nickel(II). [2]
Nickel compounds are chemical compounds containing the element nickel which is a member of the group 10 of the periodic table. Most compounds in the group have an oxidation state of +2. Nickel is classified as a transition metal with nickel(II) having much chemical behaviour in common with iron(II) and cobalt(II).
Nickel thorium nitrate has formula NiTh(NO 3) 6 · 8 H 2 O. Nickel atoms can be substituted by other ions with radius 0.69 to 0.83 Å. The nitrates are coordinated on the thorium atom and the water to the nickel. Enthalp of solution of the octahydrate is 7 kJ/mol. Enthalpy of formation is -4360 kJ/mol.
[10] Nickel nitrate commonly crystallises with six water molecules, [1] but can also be anhydrous, or with two, four or nine waters. [11] triphenylphosphine oxide nickel nitrate [(C 6 H 6) 3 PO] 2 Ni(NO 3) 2 is non ionic, with nitrato as a ligand. It can be made from nickel perchlorate. It is yellow and melts at 266 °C. [12]
The melting point of the alkali metal nitrates tends to increase from 255 °C to 414 °C (with an anomaly for rubidium being not properly aligned in the series) as the atomic mass and the ionic radius (naked cation) of the alkaline metal increases, going down in the column. Similarly, but not presented here in the table, the solubility of these ...
At 10 mg/m 3, nickel is immediately dangerous to life and health. [143] Nickel carbonyl [Ni(CO) 4] is an extremely toxic gas. The toxicity of metal carbonyls is a function of both the toxicity of the metal and the off-gassing of carbon monoxide from the carbonyl functional groups; nickel carbonyl is also explosive in air. [144] [145]