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  2. Ionic radius - Wikipedia

    en.wikipedia.org/wiki/Ionic_radius

    Ionic radius, r ion, is the radius of a monatomic ion in an ionic crystal structure. Although neither atoms nor ions have sharp boundaries, they are treated as if they were hard spheres with radii such that the sum of ionic radii of the cation and anion gives the distance between the ions in a crystal lattice .

  3. Pauling's rules - Wikipedia

    en.wikipedia.org/wiki/Pauling's_rules

    For typical ionic solids, the cations are smaller than the anions, and each cation is surrounded by coordinated anions which form a polyhedron.The sum of the ionic radii determines the cation-anion distance, while the cation-anion radius ratio + / (or /) determines the coordination number (C.N.) of the cation, as well as the shape of the coordinated polyhedron of anions.

  4. Cation-anion radius ratio - Wikipedia

    en.wikipedia.org/wiki/Cation-anion_radius_ratio

    In condensed matter physics and inorganic chemistry, the cation-anion radius ratio can be used to predict the crystal structure of an ionic compound based on the relative size of its atoms. It is defined as the ratio of the ionic radius of the positively charged cation to the ionic radius of the negatively charged anion in a cation-anion ...

  5. Ion - Wikipedia

    en.wikipedia.org/wiki/Ion

    Forming an ionic bond, Li and F become Li + and F − ions. An ion (/ ˈ aɪ. ɒ n,-ən /) [1] is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge ...

  6. Kapustinskii equation - Wikipedia

    en.wikipedia.org/wiki/Kapustinskii_equation

    K = 1.20200 × 10 −4 J·m·mol −1: d = 3.45 × 10 −11 m ν is the number of ions in the empirical formula, z + and z − are the numbers of elementary charge on the cation and anion, respectively, and r + and r − are the radii of the cation and anion, respectively, in meters.

  7. Goldschmidt tolerance factor - Wikipedia

    en.wikipedia.org/wiki/Goldschmidt_Tolerance_Factor

    r B is the radius of the B cation. r O is the radius of the anion (usually oxygen). In an ideal cubic perovskite structure, the lattice parameter (i.e., length) of the unit cell (a) can be calculated using the following equation: [ 1 ]

  8. Atomic radius - Wikipedia

    en.wikipedia.org/wiki/Atomic_radius

    In principle, the spacing between two adjacent oppositely charged ions (the length of the ionic bond between them) should equal the sum of their ionic radii. [13] Covalent radius: the nominal radius of the atoms of an element when covalently bound to other atoms, as deduced from the separation between the atomic nuclei in molecules. In ...

  9. Ionic potential - Wikipedia

    en.wikipedia.org/wiki/Ionic_potential

    Ionic potential is the ratio of the electrical charge (z) to the radius (r) of an ion. [1]= = As such, this ratio is a measure of the charge density at the surface of the ion; usually the denser the charge, the stronger the bond formed by the ion with ions of opposite charge.