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The van Deemter equation is a hyperbolic function that predicts that there is an optimum velocity at which there will be the minimum variance per unit column length and, thence, a maximum efficiency. The van Deemter equation was the result of the first application of rate theory to the chromatography elution process.
The components of the sample move through the column, each at a different velocity, which are a function of specific physical interactions with the adsorbent, the stationary phase. The velocity of each component depends on its chemical nature, on the nature of the stationary phase (inside the column) and on the composition of the mobile phase.
In dispersive media the phase velocity is not necessarily the same as the group velocity. The phase velocity varies with frequency. The phase velocity is the rate at which the phase of the wave propagates in space. The group velocity is the rate at which the wave envelope, i.e. the changes in amplitude, propagates. The wave envelope is the ...
A review by Berthod [19] studied the combined theories presented above and applied the Knox equation to independently determine the cause of the reduced efficiency. The Knox equation is commonly used in HPLC to describe the different contributions to overall band broadening of a solute. The Knox equation is expressed as: h = An^(1/3)+ B/n + Cn ...
There are two main descriptions of motion: dynamics and kinematics.Dynamics is general, since the momenta, forces and energy of the particles are taken into account. In this instance, sometimes the term dynamics refers to the differential equations that the system satisfies (e.g., Newton's second law or Euler–Lagrange equations), and sometimes to the solutions to those equations.
In physics, linearity is a property of the differential equations governing many systems; for instance, the Maxwell equations or the diffusion equation. [ 3 ] Linearity of a homogenous differential equation means that if two functions f and g are solutions of the equation, then any linear combination af + bg is, too.
A twist is a screw used to represent the velocity of a rigid body as an angular velocity around an axis and a linear velocity along this axis. All points in the body have the same component of the velocity along the axis, however the greater the distance from the axis the greater the velocity in the plane perpendicular to this axis.
the resultant velocity of the bubble. The Hadamard–Rybczynski equation can be derived from the Navier–Stokes equations by considering only the buoyancy force and drag force acting on the moving bubble. The surface tension force and inertia force of the bubble are neglected. [1]