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Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to the anti-Markovnikov addition, i.e. give the 1-bromo derivatives. [2] 1-Bromobutane can also be prepared from butanol by treatment with hydrobromic acid: [3] CH 3 (CH 2) 3 OH + HBr → CH 3 (CH 2) 3 Br + H 2 O
2-Butyne is of interest to physical chemists because of its very low torsional barrier and the problem of determining that barrier using high-resolution infrared spectroscopy. Analysis of its spectrum [ 3 ] leads to a determination that the torsional barrier is only 6 cm −1 (1.2 × 10 −22 J or 72 J mol −1 ).
Bromobutane (molecular formula: C 4 H 9 Br, molar mass: 137.02 g/mol) may refer to either of two chemical compounds: 1-Bromobutane (n-butyl bromide) 2-Bromobutane (sec-butyl bromide or methylethylbromomethane)
2-Bromobutane is an isomer of 1-bromobutane. Both compounds share the molecular formula C 4 H 9 Br. 2-Bromobutane is also known as sec-butyl bromide or methylethylbromomethane. Because it contains bromine, a halogen, it is part of a larger class of compounds known as alkyl halides. It is a colorless liquid with a pleasant odor.
132.42 J/(mol K) –262 °C to –3 °C Gas properties Std enthalpy change of formation, Δ f H o gas –124.7 kJ/mol Standard molar entropy, S o gas: 310.23 J/(mol K) Enthalpy of combustion, Δ c H o –2877.5 kJ/mol Heat capacity, c p: 98.49 J/(mol K) at 25 °C n-butane van der Waals' constants [3] a = 1466.2 L 2 kPa/mol 2 b = 0.1226 liter ...
Molar mass: 151.047 g·mol −1 Appearance colorless liquid Density: 1.199 g mL −1 [2] Melting point: −105.5 °C; −157.8 °F; 167.7 K ... 1-Bromo-2,2 ...
tert-Butyl bromide (also referred to as 2-bromo-2-methylpropane) is an organic compound with the formula Me 3 CBr (Me = methyl). The molecule features a tert-butyl group attached to a bromide substituent. This organobromine compound is used as a standard reagent in synthetic organic chemistry. It is a colorless liquid.
2-Methyl-2-butene, 2m2b, 2-methylbut-2-ene, beta-isoamylene, or Trimmethylethylene is an alkene hydrocarbon with the molecular formula C 5 H 10. Used as a free radical scavenger in trichloromethane (chloroform) and dichloromethane (methylene chloride). It is also used to scavenge hypochlorous acid (HOCl) in the Pinnick oxidation.