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The generally poor processability of aromatic polymers (for example, a high melting point and a low solubility) also limits the available options for synthesis and may require strong electron-donating co-solvents like HFIP or TFA for analysis (e. g. 1 H NMR spectroscopy) which themselves can introduce further practical limitations.
Dipole bonding is not as strong as hydrogen bonding, so a polyester's melting point and strength are lower than Kevlar's , but polyesters have greater flexibility. Polymers with non-polar units such as polyethylene interact only through weak Van der Waals forces. As a result, they typically have lower melting temperatures than other polymers.
When above the melting temperature but below the clearing point, the thermotropic LCPs will form liquid crystals. Above the clearing point, the melt will be isotropic and clear again. Frozen liquid crystals can be obtained by quenching liquid crystal polymers below the glass transition temperature. Copolymerization can be used to adjust the ...
Crystallization of polymers is a process associated with partial alignment of their molecular chains. These chains fold together and form ordered regions called lamellae, which compose larger spheroidal structures named spherulites. [1] [2] Polymers can crystallize upon cooling from melting, mechanical stretching or solvent evaporation ...
In many countries PET bottles are recycled to a substantial degree, [60] for example about 75% in Switzerland. [62] The term rPET is commonly used to describe the recycled material, though it is also referred to as R-PET or post-consumer PET (POSTC-PET). [63] [64] The prime uses for recycled PET are polyester fiber, strapping, and non-food ...
Polyester resins are synthetic resins formed by the reaction of dibasic organic acids and polyhydric alcohols. Maleic anhydride is a commonly used raw material with diacid functionality in unsaturated polyester resins. [1] Unsaturated polyester resins are used in sheet moulding compound, bulk moulding compound and the toner of laser printers.
Polycaprolactone (PCL) is a synthetic, semi-crystalline, biodegradable polyester with a melting point of about 60 °C and a glass transition temperature of about −60 °C. [2] [3] The most common use of polycaprolactone is in the production of speciality polyurethanes.
For example, the melting point of silicon at ambient pressure (0.1 MPa) is 1415 °C, but at pressures in excess of 10 GPa it decreases to 1000 °C. [13] Melting points are often used to characterize organic and inorganic compounds and to ascertain their purity. The melting point of a pure substance is always higher and has a smaller range than ...