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2. Wetting transition - Wikipedia

   en.wikipedia.org/wiki/Wetting_transition

   It is well accepted that the Cassie air trapping wetting regime corresponds to a higher energetic state, and the Cassie–Wenzel transition is irreversible. [14] However, the mechanism of the transition remains unclear. It was suggested that the Cassie–Wenzel transition occurs via a nucleation mechanism starting from the drop center. [15]

3. Wetting - Wikipedia

   en.wikipedia.org/wiki/Wetting

   The Wenzel model is valid between θ C and π/2. If the contact angle is less than Θ C, the penetration front spreads beyond the drop and a liquid film forms over the surface. Figure 11 depicts the transition from the Wenzel state to the surface film state. The film smoothes the surface roughness and the Wenzel model no longer applies.

4. Cassie's law - Wikipedia

   en.wikipedia.org/wiki/Cassie's_law

   Cassie's law, or the Cassie equation, describes the effective contact angle θ c for a liquid on a chemically heterogeneous surface, i.e. the surface of a composite material consisting of different chemistries, that is, non-uniform throughout. [1]

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