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The iron compounds produced on the largest scale in industry are iron(II) sulfate (FeSO 4 ·7H 2 O) and iron(III) chloride (FeCl 3). The former is one of the most readily available sources of iron(II), but is less stable to aerial oxidation than Mohr's salt ((NH 4) 2 Fe(SO 4) 2 ·6H 2 O). Iron(II) compounds tend to be oxidized to iron(III ...
In function of the geochemical conditions prevailing in the environment of the corroding steel, iron(II) hydroxide and green rust can progressively transform in iron(II,III) oxide, or if bicarbonate ions are present in solution, they can also evolve towards more stable carbonate phases such as iron carbonate (FeCO 3), or iron(II ...
The bicarbonate ion (hydrogencarbonate ion) is an anion with the empirical formula HCO − 3 and a molecular mass of 61.01 daltons; it consists of one central carbon atom surrounded by three oxygen atoms in a trigonal planar arrangement, with a hydrogen atom attached to one of the oxygens.
Iron(III) oxide is a product of the oxidation of iron. It can be prepared in the laboratory by electrolyzing a solution of sodium bicarbonate, an inert electrolyte, with an iron anode: 4 Fe + 3 O 2 + 2 H 2 O → 4 FeO(OH) The resulting hydrated iron(III) oxide, written here as FeO(OH), dehydrates around 200 °C. [18] [19] 2 FeO(OH) → Fe 2 O 3 ...
Potassium ferrioxalate contains the iron(III) complex [Fe(C 2 O 4) 3] 3−. In chemistry, iron(III) or ferric refers to the element iron in its +3 oxidation state. Ferric chloride is an alternative name for iron(III) chloride (FeCl 3). The adjective ferrous is used instead for iron(II) salts, containing the cation Fe 2+.
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Iron(II) carbonate, or ferrous carbonate, is a chemical compound with formula FeCO 3 , that occurs naturally as the mineral siderite . At ordinary ambient temperatures, it is a green-brown ionic solid consisting of iron(II) cations Fe 2+
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