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  2. Fajans' rules - Wikipedia

    en.wikipedia.org/wiki/Fajans'_rules

    Although the bond in a compound like X+Y- may be considered to be 100% ionic, it will always have some degree of covalent character. When two oppositely charged ions (X+ and Y-) approach each other, the cation attracts electrons in the outermost shell of the anion but repels the positively charged nucleus.

  3. IUPAC nomenclature of inorganic chemistry - Wikipedia

    en.wikipedia.org/wiki/IUPAC_nomenclature_of...

    Hydrates are ionic compounds that have absorbed water. They are named as the ionic compound followed by a numerical prefix and -hydrate. The numerical prefixes used are listed below (see IUPAC numerical multiplier): mono-di-tri-tetra-penta-hexa-hepta-octa-nona-deca-For example, CuSO 4 ·5H 2 O is "copper(II) sulfate pentahydrate".

  4. Lewis structure - Wikipedia

    en.wikipedia.org/wiki/Lewis_structure

    When Be is bonded with 2 other atoms, or when B and Al are bonded with 3 other atoms, they do not form full valence shells. Assume single bonds and use the actual bond number to calculate lone pairs. Expanded Octet (only occurs for elements in Groups 3-8) Bond calculation will provide too few bonds for the number of atoms in the molecule.

  5. Covalent bond classification method - Wikipedia

    en.wikipedia.org/wiki/Covalent_bond...

    However, these ligands also form dative covalent bonds like the L-type. [2] This type of ligand is not usually used because in certain situations it can be written in terms of L and X. For example, if a Z ligand is accompanied by an L type, it can be written as X 2. Examples of these ligands are Lewis acids, such as BR 3. [3]

  6. Charge-shift bond - Wikipedia

    en.wikipedia.org/wiki/Charge-shift_bond

    For heteronuclear bonds, A−X, Pauling estimated the covalent contribution to the bond dissociation energy as being the mean of the bond dissociation energies of homonuclear A−A and X−X bonds. The difference between the mean and the observed bond energy was assumed to be due to the ionic contribution. The calculation for HCl is shown below ...

  7. Electron counting - Wikipedia

    en.wikipedia.org/wiki/Electron_counting

    ionic counting: Fe(0) contributes 8 electrons, each CO contributes 2 each: 8 + 2 × 5 = 18 valence electrons conclusions: this is a special case, where ionic counting is the same as neutral counting, all fragments being neutral. Since this is an 18-electron complex, it is expected to be isolable compound. Ferrocene, (C 5 H 5) 2 Fe, for the ...

  8. Intramolecular force - Wikipedia

    en.wikipedia.org/wiki/Intramolecular_force

    The classical model identifies three main types of chemical bondsionic, covalent, and metallic — distinguished by the degree of charge separation between participating atoms. [3] The characteristics of the bond formed can be predicted by the properties of constituent atoms, namely electronegativity.

  9. Simplified Molecular Input Line Entry System - Wikipedia

    en.wikipedia.org/wiki/Simplified_Molecular_Input...

    When alternating single-double bonds are present, the groups are larger than two, with the middle directional symbols being adjacent to two double bonds. For example, the common form of (2,4)-hexadiene is written C/C=C/C=C/C. Beta-carotene, with the eleven double bonds highlighted.