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The hot water process is operated at a temperature range of 160 to 240 degrees Celsius in order to maintain the liquid phase. This is done above the normal boiling point of water to increase the solubilization of the hemicellulose and the depolymerization of polysaccharides. [22]
Glucomannan is a water-soluble polysaccharide that is considered a dietary fiber.It is a hemicellulose component in the cell walls of some plant species. Glucomannan is a food additive used as an emulsifier and thickener.
These water-soluble form, bile acids e.g., deoxycholic and lithocholic are adsorbed to dietary fiber and an increased fecal loss of sterols, dependent in part on the amount and type of fiber. A further factor is an increase in the bacterial mass and activity of the ileum as some fibers e.g., pectin are digested by bacteria.
The degradation of mannans (and many related forms of hemicellulose) has been well studied. The hydrolysis of the main mannan backbone is catalyzed by various enzymes including β-mannosidase, β-glucosidase, and β-mannase. The side chains are degraded by esterases and α-galactosidase. [1]
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Next to cellulose hemicellulose is the second most abundant source of carbohydrates in a plant. [12] cellulose is a homopolymer of glucose. It is very poorly soluble in most solvents, so glucose is extracted through chemical and biological breakdown achieved by cellulolytic enzymes. [12]
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The major constituents of natural fibers (lignocelluloses) are cellulose, hemicellulose, lignin, pectin and ash. The percentage of each component varies for each different type of fiber, however, generally, are around 60-80% cellulose, 5–20% lignin, and 20% of moisture, besides hemicellulose and a small percent of residual chemical components.