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a) sinusoidal, b) skewed and c) asymmetric wave shape. Sinusoidal waves (or linear waves) are waves having equal height and duration during the crest and the trough, and they can be mirrored in both the crest and the trough. Due to Non-linear effects, waves can transform from sinusoidal to a skewed and asymmetric shape.
A positive non-linear effect, (+)-NLE, is present in an asymmetric reaction which demonstrates a higher product ee (ee product) than predicted by an ideal linear situation (Figure 1). [4] It is often referred to as asymmetric amplification , a term coined by Oguni and co-workers. [ 4 ]
Asymmetry is the absence of, or a violation of, symmetry (the property of an object being invariant to a transformation, such as reflection). [1] Symmetry is an important property of both physical and abstract systems and it may be displayed in precise terms or in more aesthetic terms. [2]
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
In mathematics and science, a nonlinear system (or a non-linear system) is a system in which the change of the output is not proportional to the change of the input. [1] [2] Nonlinear problems are of interest to engineers, biologists, [3] [4] [5] physicists, [6] [7] mathematicians, and many other scientists since most systems are inherently nonlinear in nature. [8]
Fitting of a noisy curve by an asymmetrical peak model, with an iterative process (Gauss–Newton algorithm with variable damping factor α).Curve fitting [1] [2] is the process of constructing a curve, or mathematical function, that has the best fit to a series of data points, [3] possibly subject to constraints.
The first nonlinear optical effect to be predicted was two-photon absorption, by Maria Goeppert Mayer for her PhD in 1931, but it remained an unexplored theoretical curiosity until 1961 and the almost simultaneous observation of two-photon absorption at Bell Labs [4] and the discovery of second-harmonic generation by Peter Franken et al. at University of Michigan, both shortly after the ...
Any non-linear differentiable function, (,), of two variables, and , can be expanded as + +. If we take the variance on both sides and use the formula [11] for the variance of a linear combination of variables (+) = + + (,), then we obtain | | + | | +, where is the standard deviation of the function , is the standard deviation of , is the standard deviation of and = is the ...