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Zirconia is also employed in the deposition of optical coatings; it is a high-index material usable from the near-UV to the mid-IR, due to its low absorption in this spectral region. In such applications, it is typically deposited by PVD. [22] In jewelry making, some watch cases are advertised as being "black zirconium oxide". [23]
The most common oxide is zirconium dioxide, ZrO 2, also known as zirconia. This clear to white-coloured solid has exceptional fracture toughness (for a ceramic) and chemical resistance, especially in its cubic form. [37] These properties make zirconia useful as a thermal barrier coating, [38] although it is also a common diamond substitute. [37]
Discovered in 1892, the yellowish monoclinic mineral baddeleyite is a natural form of zirconium oxide. [2] The high melting point of zirconia (2750 °C or 4976 °F) hinders controlled growth of single crystals. However, stabilization of cubic zirconium oxide had been realized early on, with the synthetic product stabilized zirconia introduced ...
Yttria-stabilized zirconia (YSZ) crystal structure. Yttria-stabilized zirconia (YSZ) is a ceramic in which the cubic crystal structure of zirconium dioxide is made stable at room temperature by an addition of yttrium oxide. These oxides are commonly called "zirconia" (Zr O 2) and "yttria" (Y 2 O 3), hence the name.
The incorporation of zirconium in modern converters, forming ceria-zirconia, improves the performance of the catalyst by enhancing the resistance of the material to sintering, and simultaneously increasing the ability of the oxide to accommodate oxygen vacancies in its structure. [6]
A ceramic knife made from blackened zirconia, super heated under pressure. Zirconium oxide is used due to the fact it exists in several different forms. Zirconium can be monoclinic, tetragonal or cubic in form. Cooling to the monoclinic phase after sintering causes a large volume change, which often causes stress fractures in pure zirconia.
Baddeleyite is a rare zirconium oxide mineral (ZrO 2 or zirconia), occurring in a variety of monoclinic prismatic crystal forms. It is transparent to translucent, has high indices of refraction, and ranges from colorless to yellow, green, and dark brown.
Zirconia aluminia (or zirconia toughened alumina), a combination of zirconium oxide and aluminum oxide, is part of a class of composite ceramics called AZ composites. Noted for their mechanical properties, AZ composites are commonly used in structural applications, as cutting tools, and in many medical applications.
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