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A substance is pyrophoric (from Ancient Greek: πυροφόρος, pyrophoros, 'fire-bearing') if it ignites spontaneously in air at or below 54 °C (129 °F) (for gases) or within 5 minutes after coming into contact with air (for liquids and solids). [1] Examples are organolithium compounds and triethylborane.
Division 4.2: Spontaneously Combustible . Spontaneously combustible material is: Pyrophoric Material: A pyrophoric material is a liquid or solid that, even in small quantities and without an external ignition source, can ignite within five (5) minutes after coming in contact with air when tested according to the UN Manual of Tests and Criteria.
Pages in category "Pyrophoric materials" The following 38 pages are in this category, out of 38 total. This list may not reflect recent changes. ...
Water-reactive substances [1] are those that spontaneously undergo a chemical reaction with water, often noted as generating flammable gas. [2] Some are highly reducing in nature. [ 3 ] Notable examples include alkali metals , lithium through caesium , and alkaline earth metals , magnesium through barium .
Engines, internal combustion, flammable gas powered or Engines, internal combustion, flammable liquid powered or Vehicle, flammable gas powered or Vehicle, flammable liquid powered UN 3167: 2.1: Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid UN 3168: 2.3
A pyrotechnic composition is a substance or mixture of substances designed to produce an effect by heat, light, sound, gas/smoke or a combination of these, as a result of non-detonative self-sustaining exothermic chemical reactions. Pyrotechnic substances do not rely on oxygen from external sources to sustain the reaction.
A number of fatal industrial accidents produced by combustion and detonation of leaked silane in air have been reported. [20] [21] [22] Due to weak bonds and hydrogen, silane is a pyrophoric gas (capable of autoignition at temperatures below 54 °C or 129 °F). [23]
In its standard state arsine is a colorless, denser-than-air gas that is slightly soluble in water (2% at 20 °C) [1] and in many organic solvents as well. [citation needed] Arsine itself is odorless, [5] but it oxidizes in air and this creates a slight garlic or fish-like scent when the compound is present above 0.5 ppm. [6]