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MMA is a raw material for the manufacture of other methacrylates. These derivatives include ethyl methacrylate (EMA), butyl methacrylate (BMA) and 2-ethyl hexyl methacrylate (2-EHMA). Methacrylic acid (MAA) is used as a chemical intermediate as well as in the manufacture of coating polymers, construction chemicals and textile applications.
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A colorless liquid, it is a common monomer for the preparation of acrylate polymers. [1] It is typically polymerized under free-radical conditions. [2] Ethyl methacrylate was first obtained by treating ethyl 2-hydroxyisobutyrate with phosphorus pentachloride in a dehydration reaction. [3]
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In 1960, O. Wichterle and D. Lím [7] described its use in synthesis of hydrophilic crosslinked networks, and these results had great importance for manufacture of soft contact lenses. [5] Polyhydroxyethylmethacrylate is hydrophilic: it is capable of absorbing from 10 to 600% water relative to the dry weight.
RAFT polymerization today is mainly carried out by thiocarbonylthio chain transfer agents. It was first reported by Rizzardo et al. in 1998. [6] RAFT is one of the most versatile methods of controlled radical polymerization because it is tolerant of a very wide range of functionality in the monomer and solvent, including aqueous solutions. [7]