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Thermodynamic temperature is a specifically thermodynamic concept, while the original directly measureable state variables are defined by ordinary physical measurements, without reference to thermodynamic concepts; for this reason, it is helpful to regard thermodynamic temperature as a state function.
State functions represent quantities or properties of a thermodynamic system, while non-state functions represent a process during which the state functions change. For example, the state function PV is proportional to the internal energy of an ideal gas, but the work W is the amount of energy transferred as the system performs work. Internal ...
In thermodynamics, a physical property is any property that is measurable, and whose value describes a state of a physical system. Thermodynamic properties are defined as characteristic features of a system, capable of specifying the system's state.
Equilibrium thermodynamics is the study of transfers of matter and energy in systems or bodies that, by agencies in their surroundings, can be driven from one state of thermodynamic equilibrium to another. The term 'thermodynamic equilibrium' indicates a state of balance, in which all macroscopic flows are zero; in the case of the simplest ...
In physics and chemistry, an equation of state is a thermodynamic equation relating state variables, which describe the state of matter under a given set of physical conditions, such as pressure, volume, temperature, or internal energy. [1] [2] Most modern equations of state are formulated in the Helmholtz free energy.
In thermodynamics, a state variable is an independent variable of a state function. Examples include internal energy , enthalpy , temperature , pressure , volume and entropy . Heat and work are not state functions, but process functions .
The equilibrium state of a thermodynamic system is described by specifying its "state". The state of a thermodynamic system is specified by a number of extensive quantities, the most familiar of which are volume, internal energy, and the amount of each constituent particle (particle numbers). Extensive parameters are properties of the entire ...
The state postulate is a term used in thermodynamics that defines the given number of properties to a thermodynamic system in a state of equilibrium. It is also sometimes referred to as the state principle. [1] The state postulate allows a finite number of properties to be specified in order to fully describe a state of thermodynamic equilibrium.