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The rank of coal is correlated with its geologic history, as described in Hilt's law. In the ASTM system, any coal with more than 69% fixed carbon is classified by its content of carbon and volatiles. Coal with less than 69% fixed carbon is classified by its heating value. Volatiles and carbon are on a dry mineral free base; heating value is ...
Anthracite, also known as hard coal and black coal, is a hard, compact variety of coal that has a submetallic lustre. It has the highest carbon content, the fewest impurities, and the highest energy density of all types of coal and is the highest ranking of coals.
Additionally, specific physical and mechanical properties of coal and particular carbonization properties The calorific value Q of coal [kJ/kg] is the heat liberated by its complete combustion with oxygen. Q is a complex function of the elemental composition of the coal [citation needed]. Q can be determined experimentally using calorimeters.
Note that the especially high molar values, as for paraffin, gasoline, water and ammonia, result from calculating specific heats in terms of moles of molecules. If specific heat is expressed per mole of atoms for these substances, none of the constant-volume values exceed, to any large extent, the theoretical Dulong–Petit limit of 25 J⋅mol ...
Smokeless fuels generally have a high calorific value, with that of anthracite being greater than dry wood for example, and many smokeless briquettes are made from this type of coal. Thus anthracite has a calorific value of 32.5 MJ/kg compared with that of dry wood of about 21 MJ/kg.
Young coals (brown coal, lignite) are not black. The two main black coals are bituminous, which is more abundant, and anthracite. The % carbon in coal follows the order anthracite > bituminous > lignite > brown coal. The fuel value of coal varies in the same order. Some anthracite deposits contain pure carbon in the form of graphite.
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The heating value (or energy value or calorific value) of a substance, usually a fuel or food (see food energy), is the amount of heat released during the combustion of a specified amount of it. The calorific value is the total energy released as heat when a substance undergoes complete combustion with oxygen under standard conditions.