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The mathematical by-product of this calculation is the mass–energy equivalence formula, that mass and energy are essentially the same thing: [14]: 51 [15]: 121 = = At a low speed (v ≪ c), the relativistic kinetic energy is approximated well by the classical kinetic energy.
In the second step of the BO approximation the nuclear kinetic energy T n is reintroduced and the Schrödinger equation with Hamiltonian ^ = = = + (, …,) is considered. One would like to recognize in its solution: the motion of the nuclear center of mass (3 degrees of freedom), the overall rotation of the molecule (3 degrees of freedom), and ...
m = mass of each molecule (all molecules are identical in kinetic theory), γ ( p ) = Lorentz factor as function of momentum (see below) Ratio of thermal to rest mass-energy of each molecule: θ = k B T / m c 2 {\displaystyle \theta =k_{\text{B}}T/mc^{2}}
The Hamiltonian of a system represents the total energy of the system; that is, the sum of the kinetic and potential energies of all particles associated with the system. . The Hamiltonian takes different forms and can be simplified in some cases by taking into account the concrete characteristics of the system under analysis, such as single or several particles in the system, interaction ...
Thus, the ratio of the kinetic energy to the absolute temperature of an ideal monatomic gas can be calculated easily: per mole: 12.47 J/K; per molecule: 20.7 yJ/K = 129 μeV/K; At standard temperature (273.15 K), the kinetic energy can also be obtained: per mole: 3406 J; per molecule: 5.65 zJ = 35.2 meV.
The Boltzmann equation can be used to derive the fluid dynamic conservation laws for mass, charge, momentum, and energy. [ 8 ] : 163 For a fluid consisting of only one kind of particle, the number density n is given by n = ∫ f d 3 p . {\displaystyle n=\int f\,d^{3}\mathbf {p} .}
The macroscopic energy equation for infinitesimal volume used in heat transfer analysis is [6] = +, ˙, where q is heat flux vector, −ρc p (∂T/∂t) is temporal change of internal energy (ρ is density, c p is specific heat capacity at constant pressure, T is temperature and t is time), and ˙ is the energy conversion to and from thermal ...
where q is the charge, is the mean free time, m * is the effective mass, and v F is the Fermi velocity of the charge carrier. The Fermi velocity can easily be derived from the Fermi energy via the non-relativistic kinetic energy equation.