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4-Aminophenol (or para-aminophenol or p-aminophenol) is an organic compound with the formula H 2 NC 6 H 4 OH. Typically available as a white powder, [ 3 ] it is commonly used as a developer for black-and-white film , marketed under the name Rodinal .
The mechanism of the Bamberger rearrangement proceeds from the monoprotonation of N-phenylhydroxylamine 1.N-protonation 2 is favored, but unproductive. O-protonation 3 can form the nitrenium ion 4, which can react with nucleophiles (H 2 O) to form the desired 4-aminophenol 5.
The classical methods for the production of paracetamol involve the acetylation of 4-aminophenol with acetic anhydride as the last step. They differ in how 4-aminophenol is prepared. In one method, nitration of phenol with nitric acid affords 4-nitrophenol, which is reduced to 4-aminophenol by hydrogenation over Raney nickel.
Metol (or Elon) is a trade name for the organic compound with the formula [HOC 6 H 4 NH 2 (CH 3)] 2 HSO 4. It is the sulfate salt of N -methylaminophenol. This colourless salt is a popular photographic developer used in monochrome photography .
4-Nitrophenol is an intermediate in the synthesis of paracetamol. It is reduced to 4-aminophenol, then acetylated with acetic anhydride. [6] 4-Nitrophenol is used as the precursor for the preparation of phenetidine and acetophenetidine, indicators, and raw materials for fungicides. Bioaccumulation of this compound rarely occurs.
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1/4 cup unsalted butter, cubed. 1/4 cup all-purpose flour. Salt, as needed. Combine the soup base and hot water in a 2-cup measuring cup. Set aside. Alternatively, you can use 2 cups of chicken or ...