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The manganese (Mn) atom has a 3d 5 electron configuration with five unpaired electrons all of parallel spin, corresponding to a 6 S ground state. [4] The superscript 6 is the value of the multiplicity , corresponding to five unpaired electrons with parallel spin in accordance with Hund's rule.
[4] [5] It may be considered a 2-dimensional parallel array of very small continuous-dynode electron multipliers, built together and powered in parallel. Each microchannel is generally parallel-walled, not tapered or funnel-like. MCPs are constructed from lead glass and carry a resistance of 10 9 Ω between each electrode. Each channel has a ...
For example, in copper 29 Cu, according to the Madelung rule, the 4s subshell (n + l = 4 + 0 = 4) is occupied before the 3d subshell (n + l = 3 + 2 = 5). The rule then predicts the electron configuration 1s 2 2s 2 2p 6 3s 2 3p 6 3d 9 4s 2, abbreviated [Ar] 3d 9 4s 2 where [Ar] denotes the configuration of argon, the preceding noble gas.
Each has two electrons of opposite spin in the π* level so that S = 0 and the multiplicity is 2S + 1 = 1 in consequence. In the first excited state, the two π* electrons are paired in the same orbital, so that there are no unpaired electrons. In the second excited state, however, the two π* electrons occupy different orbitals with opposite spin.
Close to an aperture or atoms, often called the "sample", the electron wave would be described in terms of near field or Fresnel diffraction. [12]: Chpt 7-8 This has relevance for imaging within electron microscopes, [1]: Chpt 3 [2]: Chpt 3-4 whereas electron diffraction patterns are measured far from the sample, which is described as far-field or Fraunhofer diffraction. [12]:
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That is, the spin of the excited electron is still paired with the ground state electron (a pair of electrons in the same energy level must have opposite spins, per the Pauli exclusion principle). In a triplet state the excited electron is no longer paired with the ground state electron; that is, they are parallel (same spin). Since excitation ...