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The +M effect, also known as the positive mesomeric effect, occurs when the substituent is an electron donating group. The group must have one of two things: a lone pair of electrons, or a negative charge. In the +M effect, the pi electrons are transferred from the group towards the conjugate system, increasing the density of the system.
Baader–Meinhof effect; Barnum effect; Bezold effect; Birthday-number effect; Boomerang effect; Bouba/kiki effect; Bystander effect; Cheerleader effect; Cinderella effect; Cocktail party effect; Contrast effect; Coolidge effect; Crespi effect; Cross-race effect; Curse of knowledge; Diderot effect; Dunning–Kruger effect; Einstellung effect ...
Audience effect (psychology) (social psychology) Auger effect (atomic physics) (foundational quantum physics) Aureole effect (atmospheric optical phenomena) (scientific terminology) Autler–Townes effect (atomic, molecular, and optical physics) (atomic physics) (quantum optics) Autokinetic effect (vision) Avalanche effect (cryptography)
However, another effect that plays a role is the +M effect which adds electron density back into the benzene ring (thus having the opposite effect of the -I effect but by a different mechanism). This is called the mesomeric effect (hence +M) and the result for fluorine is that the +M effect approximately cancels out the -I effect.
Positivity effect (Socioemotional selectivity theory) That older adults favor positive over negative information in their memories. See also euphoric recall: Primacy effect: Where an item at the beginning of a list is more easily recalled. A form of serial position effect. See also recency effect and suffix effect. Processing difficulty effect
The next set of substituents are the halogens, for which the substituent effect is still positive but much more modest. The reason for this is that while the inductive effect is still negative, the mesomeric effect is positive, causing partial cancellation. The data also show that for these substituents, the meta effect is much larger than the ...
In chemistry, mesoionic compounds are one in which a heterocyclic structure is dipolar and where both the negative and the positive charges are delocalized. [1] A completely uncharged structure cannot be written and mesoionic compounds cannot be represented satisfactorily by any one mesomeric structure. [1] Mesoionic compounds are a subclass of ...
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