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At high temperatures, usually above 1300 °C (2600 °F), molecular nitrogen (N 2) and oxygen (O 2) in the combustion air dissociate into their atomic states and participate in a series of reactions. The three principal reactions (the extended Zel'dovich mechanism) producing thermal NO x are: N 2 + O ⇌ NO + N N + O 2 ⇌ NO + O N + OH· ⇌ NO ...
Nitrification is a process of nitrogen compound oxidation (effectively, loss of electrons from the nitrogen atom to the oxygen atoms), and is catalyzed step-wise by a series of enzymes. 2 NH 4 + + 3 O 2 2 NO 2 − + 4 H + + 2 H 2 O {\displaystyle {\ce {2NH4+ + 3O2 -> 2NO2- + 4H+ + 2H2O}}} ( Nitrosomonas , Comammox )
In the NO − 3 anion, the oxidation state of the central nitrogen atom is V (+5). This corresponds to the highest possible oxidation number of nitrogen. Nitrate is a potentially powerful oxidizer as evidenced by its explosive behaviour at high temperature when it is detonated in ammonium nitrate (NH 4 NO 3), or black powder, ignited by the shock wave of a primary explosive.
Nitric oxide (nitrogen oxide or nitrogen monoxide [1]) is a colorless gas with the formula NO. It is one of the principal oxides of nitrogen . Nitric oxide is a free radical : it has an unpaired electron , which is sometimes denoted by a dot in its chemical formula ( • N=O or • NO).
The chemical element nitrogen is one of the most abundant elements in the universe and can form many compounds. It can take several oxidation states; but the most common oxidation states are -3 and +3. Nitrogen can form nitride and nitrate ions. It also forms a part of nitric acid and nitrate salts.
Nitrite oxidoreductase (NOR or NXR) is an enzyme involved in nitrification.It is the last step in the process of aerobic ammonia oxidation, which is carried out by two groups of nitrifying bacteria: ammonia oxidizers such as Nitrosospira, Nitrosomonas, and Nitrosococcus convert ammonia to nitrite, while nitrite oxidizers such as Nitrobacter and Nitrospira oxidize nitrite to nitrate.
Nitrogen is present in the environment in a wide variety of chemical forms including organic nitrogen, ammonium (NH + 4), nitrite (NO − 2), nitrate (NO − 3), nitrous oxide (N 2 O), nitric oxide (NO) or inorganic nitrogen gas (N 2). Organic nitrogen may be in the form of a living organism, humus or in the intermediate products of organic ...
An example of the ecological importance of anaerobic respiration is the use of nitrate as a terminal electron acceptor, or dissimilatory denitrification, which is the main route by which fixed nitrogen is returned to the atmosphere as molecular nitrogen gas. [3] The denitrification process is also very important in host-microbe interactions.