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  2. Bicyclobutane - Wikipedia

    en.wikipedia.org/wiki/Bicyclobutane

    The intermediate 1-bromo-3-chlorocyclobutane can also be prepared via a modified Hunsdiecker reaction from 3-chlorocyclobutanecarboxylic acid using mercuric oxide and bromine: [4] A synthetic approach to bicyclobutane derivatives involves ring closure of a suitably substituted 2-bromo-1-(chloromethyl)cyclopropane with magnesium in THF. [5]

  3. Bicyclic molecule - Wikipedia

    en.wikipedia.org/wiki/Bicyclic_molecule

    The numbers are sometimes omitted in unambiguous cases. For example, bicyclo[1.1.0]butane is typically called simply bicyclobutane. The heterocyclic molecule DABCO has a total of 8 atoms in its bridged structure, hence the root name octane. Here the two bridgehead atoms are nitrogen instead of carbon atoms.

  4. Diradicaloid - Wikipedia

    en.wikipedia.org/wiki/Diradicaloid

    Cyclobutane-1,3-diyl is the planar four-membered carbon ring species with radical character localized at the 1 and 3 positions. The singlet cyclobutane-1,3-diyl is predicted to be the transition state for the ring inversion of bicyclobutane, proceeding via homolytic cleavage of the transannular carbon-carbon bond (Figure 3).

  5. Reaction intermediate - Wikipedia

    en.wikipedia.org/wiki/Reaction_intermediate

    In chemistry, a reaction intermediate, or intermediate, is a molecular entity arising within the sequence of a stepwise chemical reaction. It is formed as the reaction product of an elementary step, from the reactants and/or preceding intermediates, but is consumed in a later step. It does not appear in the chemical equation for the overall ...

  6. Cyclobutane - Wikipedia

    en.wikipedia.org/wiki/Cyclobutane

    Cyclobutane is a cycloalkane and organic compound with the formula (CH 2) 4.Cyclobutane is a colourless gas and is commercially available as a liquefied gas.Derivatives of cyclobutane are called cyclobutanes.

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  8. Metallacycle - Wikipedia

    en.wikipedia.org/wiki/Metallacycle

    Structure of the platinacyclobutane complex PtC 3 H 6 derived from activation of cyclopropane. [1]In organometallic chemistry, a metallacycle is a derivative of a carbocyclic compound wherein a metal has replaced at least one carbon center; [2] [3] this is to some extent similar to heterocycles.

  9. Glossary of chemistry terms - Wikipedia

    en.wikipedia.org/wiki/Glossary_of_chemistry_terms

    Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...