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Interactions between carbonyl groups and other substituents were found in a study of collagen. [3] Substituents can affect carbonyl groups by addition or subtraction of electron density by means of a sigma bond. [4] ΔHσ values are much greater when the substituents on the carbonyl group are more electronegative than carbon. [4] A carbonyl ...
The carbonyl group is polar because the electronegativity of the oxygen is greater than that for carbon. Thus, ketones are nucleophilic at oxygen and electrophilic at carbon. Because the carbonyl group interacts with water by hydrogen bonding, ketones are typically more soluble in water than the related methylene compounds. Ketones are hydrogen ...
Polar liquids have a tendency to be more viscous than nonpolar liquids. [citation needed] For example, nonpolar hexane is much less viscous than polar water. However, molecule size is a much stronger factor on viscosity than polarity, where compounds with larger molecules are more viscous than compounds with smaller molecules.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Metal carbonyls are soluble in nonpolar and polar organic solvents such as benzene, diethyl ether, acetone, glacial acetic acid, and carbon tetrachloride. Some salts of cationic and anionic metal carbonyls are soluble in water or lower alcohols. [10]
Many carbonyl compounds exhibit keto–enol tautomerism. This effect is especially pronounced in 1,3-dicarbonyl compounds that can form hydrogen-bonded enols. The equilibrium constant is dependent upon the solvent polarity, with the cis-enol form predominating at low polarity and the diketo form predominating at high polarity.
Polar solvents can be used to dissolve inorganic or ionic compounds such as salts. The conductivity of a solution depends on the solvation of its ions. Nonpolar solvents cannot solvate ions, and ions will be found as ion pairs. Hydrogen bonding among solvent and solute molecules depends on the ability of each to accept H-bonds, donate H-bonds ...
Plus, when functional groups are more electronegative than atoms they attach to, the functional groups will become polar, and the otherwise nonpolar molecules containing these functional groups become polar and so become soluble in some aqueous environment.