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However, the lipophilic "tails" of surfactant molecules have less contact with water when they are part of a micelle—this being the basis for the energetic drive for micelle formation. In a micelle, the hydrophobic tails of several surfactant molecules assemble into an oil-like core, the most stable form of which having no contact with water.
A micellar cubic phase is a lyotropic liquid crystal phase formed when the concentration of micelles dispersed in a solvent (usually water) is sufficiently high that they are forced to pack into a structure having a long-ranged positional (translational) order. For example, spherical micelles a cubic packing of a body-centered cubic lattice.
The shape of a micelle is directly dependent on the packing parameter of the surfactant. Surfactants with a packing parameter of N S {\displaystyle N_{\text{S}}} ≤ 1/3 appear to have a cone-like shape which will pack together to form spherical micelles when in an aqueous environment (top in figure).
Soap is a common household amphiphilic surfactant compound. Soap mixed with water (polar, hydrophilic) is useful for cleaning oils and fats (non-polar, lipiphillic) from kitchenware, dishes, skin, clothing, etc.
Wetting agent was used as soap for cleansing purposes for thousands of years. The oldest evidence of wetting solution went back to 2800 BC in ancient Babylon. [2] The earliest credible reference of soap is in the writings of Galen, the Greek physician, around 200 AD. [11]
Sodium stearate is produced as a major component of soap upon saponification of oils and fats. The percentage of the sodium stearate depends on the ingredient fats. Tallow is especially high in stearic acid content (as the triglyceride), whereas most fats only contain a few percent. The idealized equation for the formation of sodium stearate ...
CM is the concentration of the micelle in the mobile phase (total surfactant concentration - critical micelle concentration) A plot of 1/k¢ verses CM gives a straight line in which KSW can be calculated from the intercept and KMW can be obtained from the ratio of the slope to the intercept. Finally, KSM can be obtained from the ratio of the ...
In geotechnical engineering, soil structure describes the arrangement of the solid parts of the soil and of the pore space located between them. It is determined by how individual soil granules clump, bind together, and aggregate , resulting in the arrangement of soil pores between them.