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Group 1: Alkali metals Reaction of sodium (Na) and water Reaction of potassium (K) in water. The alkali metals (Li, Na, K, Rb, Cs, and Fr) are the most reactive metals in the periodic table - they all react vigorously or even explosively with cold water, resulting in the displacement of hydrogen.
The alkali metals also react with water to form strongly alkaline hydroxides and thus should be handled with great care. The heavier alkali metals react more vigorously than the lighter ones; for example, when dropped into water, caesium produces a larger explosion than potassium if the same number of moles of each metal is used.
Metal aqua ions are often involved in the formation of complexes. The reaction may be written as pM x+ (aq) + qL y− → [M p L q] (px-qy)+ In reality this is a substitution reaction in which one or more water molecules from the first hydration shell of the metal ion are replaced by ligands, L. The complex is described as an inner-sphere complex.
The most reactive metals, such as sodium, will react with cold water to produce hydrogen and the metal hydroxide: 2 Na (s) + 2 H 2 O (l) →2 NaOH (aq) + H 2 (g) Metals in the middle of the reactivity series, such as iron , will react with acids such as sulfuric acid (but not water at normal temperatures) to give hydrogen and a metal salt ...
Potassium metal can react violently with water producing KOH and hydrogen gas. 2 K(s) + 2 H 2 O(l) → 2 KOH(aq) + H 2 (g)↑ A reaction of potassium metal with water. Hydrogen is produced, and with potassium vapor, burns with a pink or lilac flame. Strongly alkaline potassium hydroxide is formed in solution.
Reaction with nitrogen. Only Be and Mg form nitrides directly. 3Be + N 2 → Be 3 N 2 3Mg + N 2 → Mg 3 N 2. Reaction with hydrogen. Alkaline earth metals react with hydrogen to generate saline hydride that are unstable in water. Ca + H 2 → CaH 2. Reaction with water. Ca, Sr, and Ba readily react with water to form hydroxide and hydrogen gas.
A basic oxide, also called a base anhydride (meaning "base without water"), is usually formed in the reaction of oxygen with metals, especially alkali (group 1) and alkaline earth (group 2) metals. Both of these groups form ionic oxides that dissolve in water to form basic solutions of the corresponding metal hydroxide: Alkali metals (Group 1)
It reacts with carbon dioxide to form lithium carbonate and oxygen. Sodium peroxide (Na 2 O 2) is a pale yellow solid that melts at 460 °C and decomposes at 657 °C. Potassium peroxide (K 2 O 2) is a yellow solid that melts at 490 °C. Rubidium peroxide (Rb 2 O 2) is produced when rubidium stands in air.