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Nickel–zinc batteries have a charge–discharge curve similar to 1.2 V NiCd or NiMH cells, but with a higher 1.6 V nominal voltage. [5]Nickel–zinc batteries perform well in high-drain applications, and may have the potential to replace lead–acid batteries because of their higher energy-to-mass ratio and higher power-to-mass ratio – as little as 25% of the mass for the same power. [6]
A nickel–metal hydride battery (NiMH or Ni–MH) is a type of rechargeable battery. The chemical reaction at the positive electrode is similar to that of the nickel–cadmium cell (NiCd), with both using nickel oxide hydroxide (NiOOH). However, the negative electrodes use a hydrogen-absorbing alloy instead of cadmium.
0.1: 12.5 × 1.6 Used in some lighted watches and some LED decorator lights (electronic tea candles). CR1220: 5012LC: 35–40: 0.1 (CR) 0.03 (BR) 12.5 × 2.0 Used in keychain LED flashlights, and in some digital cameras to keep the time and date function running even when the main battery is taken out of the camera. [146] [147] CR1225: 5020LC ...
The open-circuit voltage is 1.55 V, the average voltage during discharge is 1.25 V. [9] While the energy density is only around one third as that of a lithium battery, the distinctive virtue of the nickel–hydrogen battery is its long life: the cells handle more than 20,000 charge cycles [4] with 85% energy efficiency and 100% faradaic efficiency.
At one point, Ni–Cd batteries accounted for 8% of all portable secondary (rechargeable) battery sales in the EU, and in the UK for 9.2% (disposal) and in Switzerland for 1.3% of all portable battery sales. [7] [8] [9] In the EU the 2006 Battery Directive restricted sales of Ni–Cd batteries to consumers for portable devices.
The nine-volt PP3-size battery is commonly available in primary zinc–carbon and alkaline chemistry, in primary lithium iron disulfide and lithium manganese dioxide (sometimes designated CRV9 [2]), and in rechargeable form in nickel–cadmium (Ni–Cd), nickel–metal hydride (Ni–MH) and lithium-ion.
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