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A micelle (/ m aɪ ˈ s ɛ l /) or micella (/ m aɪ ˈ s ɛ l ə /) (pl. micelles or micellae, respectively) is an aggregate (or supramolecular assembly) of surfactant amphipathic lipid molecules dispersed in a liquid, forming a colloidal suspension (also known as associated colloidal system). [4] A typical micelle in water forms an aggregate ...
Schematic diagram of a micelle of oil in aqueous suspension, such as might occur in an emulsion of oil in water. In this example, the surfactant molecules' oil-soluble tails project into the oil (blue), while the water-soluble ends remain in contact with the water phase (red).
Schematic of a micellar solution showing spherical micelles distributed in water (solvent) and having no long-range positional order. In colloid science, a micellar solution consists of a dispersion of micelles (small particles) in a solvent (most usually water).
Bicelles are a related class of model membrane, [57] typically made of two lipids, one of which forms a lipid bilayer while the other forms an amphipathic, micelle-like assembly shielding the bilayer center from surrounding solvent molecules. Bicelles can be thought of as a segment of bilayer encapsulated and solubilized by a micelle.
The shape of a micelle is directly dependent on the packing parameter of the surfactant. Surfactants with a packing parameter of N S {\displaystyle N_{\text{S}}} ≤ 1/3 appear to have a cone-like shape which will pack together to form spherical micelles when in an aqueous environment (top in figure).
The amphiphiles' hydrocarbon tails are contained on the inside of the micelle and hence the polar-apolar interface of the aggregates has a positive mean curvature, by definition (it curves away from the polar phase). The first pure surfactant system found to exhibit three different type I (oil-in-water) micellar cubic phases was observed in the ...
Alternative names for these systems are often used, such as transparent emulsion, swollen micelle, micellar solution, and solubilized oil. More confusingly still, the term microemulsion can refer to the single isotropic phase that is a mixture of oil, water and surfactant, or to one that is in equilibrium with coexisting predominantly oil and ...
Elution ranges can be extended by several techniques including the use of organic modifiers, cyclodextrins, and mixed micelle systems. Short-chain alcohols or acetonitrile can be used as organic modifiers that decrease t M {\displaystyle t_{M}} and k 1 {\displaystyle k^{1}} to improve the resolution of analytes that co-elute with the micellar ...