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HDPE is known for its high strength-to-density ratio. [4] The density of HDPE ranges from 930 to 970 kg/m 3. [5] Although the density of HDPE is only marginally higher than that of low-density polyethylene, HDPE has little branching, giving it stronger intermolecular forces and tensile strength (38 MPa versus 21 MPa) than LDPE. [6]
The high molecular weight makes it a very tough material, but results in less efficient packing of the chains into the crystal structure as evidenced by densities of less than high-density polyethylene (for example, 0.930–0.935 g/cm 3). UHMWPE can be made through any catalyst technology, although Ziegler catalysts are most common.
These molecules are several orders of magnitude longer than those of familiar high-density polyethylene (HDPE) due to a synthesis process based on metallocene catalysts, resulting in UHMWPE molecules typically having 100,000 to 250,000 monomer units per molecule each compared to HDPE's 700 to 1,800 monomers.
High-density polyethylene (HDPE) has a very low degree of branching, is relatively stiff, and is used in applications such as bullet-proof vests. Low-density polyethylene (LDPE), on the other hand, has significant numbers of both long and short branches, is relatively flexible, and is used in applications such as plastic films. Dendrimer and ...
Even polyethylenes copolymerized with a small amount of alpha-olefins (such as 1-hexene, 1-octene, or longer) are more flexible than simple straight-chain high-density polyethylene, which has no branching. [7] The methyl branch groups on a polypropylene polymer are not long enough to make typical commercial polypropylene more flexible than ...
LDPE has SPI resin ID code 4 Schematic of LDPE branching structure. Low-density polyethylene (LDPE) is a thermoplastic made from the monomer ethylene.It was the first grade of polyethylene, produced in 1933 by Dr John C. Swallow and M.W Perrin who were working for Imperial Chemical Industries (ICI) using a high pressure process via free radical polymerization. [1]
A cross-linked polyethylene (PEX) pipe. Cross-linked polyethylene, commonly abbreviated PEX, XPE or XLPE, is a form of polyethylene with cross-links.It is used predominantly in building services pipework systems, hydronic radiant heating and cooling systems, domestic water piping, insulation for high tension (high voltage) electrical cables, and baby play mats.
Ionic polymerization generates many polymers used in daily life, such as butyl rubber, polyisobutylene, polyphenylene, polyoxymethylene, polysiloxane, polyethylene oxide, high density polyethylene, isotactic polypropylene, butadiene rubber, etc. Living anionic polymerization was developed in the 1950s.
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