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Both the negatively charged anion HO −, called hydroxide, and the neutral radical HO·, known as the hydroxyl radical, consist of an unbonded hydroxy group. According to IUPAC definitions, the term hydroxyl refers to the hydroxyl radical (·OH) only, while the functional group −OH is called a hydroxy group. [1]
Hydroxide is a diatomic anion with chemical formula OH −. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst.
The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons [2] (e.g. K + (potassium ion)) while an anion is a negatively charged ion with more electrons than protons. [3] (e.g. Cl-(chloride ion) and OH-(hydroxide
A positively charged hydrogen ion (or proton) can readily combine with other particles and therefore is only seen isolated when it is in a gaseous state or a nearly particle-free space. [1] Due to its extremely high charge density of approximately 2×10 10 times that of a sodium ion, the bare hydrogen ion cannot exist freely in solution as it ...
The hydrogen anion, H −, is a negative ion of hydrogen, that is, a hydrogen atom that has captured an extra electron. The hydrogen anion is an important constituent of the atmosphere of stars, such as the Sun. In chemistry, this ion is called hydride. The ion has two electrons bound by the electromagnetic force to a nucleus containing one proton.
That is why H + is often called a proton. This species is central to discussion of acids. Under the Brønsted–Lowry acid–base theory, acids are proton donors, while bases are proton acceptors. A bare proton, H +, cannot exist in solution or in ionic crystals because of its unstoppable attraction to other atoms or molecules with electrons.
In this case, hydroxide is a strong enough base to deprotonate the carboxylic acid because the conjugate base is more stable than the base because the negative charge is delocalized over two electronegative atoms compared to one. Using pK a values, the carboxylic
Electrolytic cell producing chlorine (Cl 2) and sodium hydroxide (NaOH) from a solution of common salt. For example, in a solution of ordinary table salt (sodium chloride, NaCl) in water, the cathode reaction will be 2 H 2 O + 2e − → 2 OH − + H 2. and hydrogen gas will bubble up; the anode reaction is 2 NaCl → 2 Na + + Cl 2 + 2e −