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Spectral line shape or spectral line profile describes the form of an electromagnetic spectrum in the vicinity of a spectral line – a region of stronger or weaker intensity in the spectrum. Ideal line shapes include Lorentzian , Gaussian and Voigt functions, whose parameters are the line position, maximum height and half-width. [ 1 ]
The pseudo-Voigt profile (or pseudo-Voigt function) is an approximation of the Voigt profile V(x) using a linear combination of a Gaussian curve G(x) and a Lorentzian curve L(x) instead of their convolution. The pseudo-Voigt function is often used for calculations of experimental spectral line shapes.
Curve fitting [1] [2] is the process of constructing a curve, or mathematical function, that has the best fit to a series of data points, [3] possibly subject to constraints. [ 4 ] [ 5 ] Curve fitting can involve either interpolation , [ 6 ] [ 7 ] where an exact fit to the data is required, or smoothing , [ 8 ] [ 9 ] in which a "smooth ...
In other words, it is the width of a spectrum curve measured between those points on the y-axis which are half the maximum amplitude. Half width at half maximum (HWHM) is half of the FWHM if the function is symmetric. The term full duration at half maximum (FDHM) is preferred when the independent variable is time.
In Fluorescence lifetime and spectral imaging, phasor can be used to visualize the spectra and decay curves. [1] [2] In this method the Fourier transformation of the spectrum or decay curve is calculated and the resulted complex number is plotted on a 2D plot where the X-axis represents the real component and the Y-axis represents the imaginary ...
Fityk is curve fitting and data analysis application, predominantly used to fit analytical, bell-shaped functions to experimental data. It is positioned to fill the gap between general plotting software and programs specific for one field, e.g. crystallography or XPS.
The red line represents the local polynomial being used to fit a sub-set of the data. The smoothed values are shown as circles. A Savitzky–Golay filter is a digital filter that can be applied to a set of digital data points for the purpose of smoothing the data, that is, to increase the precision of the data without distorting the signal ...
The cgs units of spectral radiance B ν are erg·s −1 ·sr −1 ·cm −2 ·Hz −1. The terms B and u are related to each other by a factor of 4π / c since B is independent of direction and radiation travels at speed c. The spectral radiance can also be expressed per unit wavelength λ instead of per unit frequency. In addition, the ...
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