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Aqueous iron(III) chloride serves as a one-electron oxidant illustrated by its reaction with copper(I) chloride to give copper(II) chloride and iron(II) chloride. FeCl 3 + CuCl → FeCl 2 + CuCl 2. This fundamental reaction is relevant to the use of ferric chloride solutions in etching copper.
ferric chloride may be used for etching copper or zinc plates, whereas nitric acid may be used for etching zinc or steel plates. Typical solutions are 1 part FeCl 3 to 1 part water and 1 part nitric to 3 parts water. The strength of the acid determines the speed of the etching process. The etching process is known as biting (see also spit ...
In organic chemistry, Keller's reagent is a mixture of anhydrous (glacial) acetic acid, concentrated sulfuric acid, and small amounts of ferric chloride, used to detect alkaloids. Keller's reagent can also be used to detect other kinds of alkaloids via reactions in which it produces products with a wide range of colors. [4][5][6] Cohn describes ...
Hydrated forms of ferrous chloride are generated by treatment of wastes from steel production with hydrochloric acid. Such solutions are designated "spent acid," or "pickle liquor" especially when the hydrochloric acid is not completely consumed: Fe + 2 HCl → FeCl 2 + H 2. The production of ferric chloride involves the use of ferrous chloride.
The etching progresses through the tonal scale from dark to light as the plate is moved to successively more dilute baths of ferric chloride. The image is etched onto the copperplate by the ferric chloride, creating a gravure plate with tiny "wells" of varying depth to hold ink.
Ferric. Potassium ferrioxalate contains the iron (III) complex [Fe (C2O4)3]3−. In chemistry, iron (III) or ferric refers to the element iron in its +3 oxidation state. Ferric chloride is an alternative name for iron (III) chloride (FeCl3). The adjective ferrous is used instead for iron (II) salts, containing the cation Fe 2+.
The etching line is a multi-chambered machine that has driven-wheel conveyors to move the plates and arrays of spray nozzles above and below the plates. The etchant is typically an aqueous solution of acid, frequently ferric chloride, that is heated and directed under pressure to both sides of the plate. The etchant reacts with the unprotected ...
There are many variations to this process, depending on the type of substrate being plated. Different substrates need different etching solutions, such as hydrochloric, hydrofluoric, and sulfuric acids. Ferric chloride is also popular for the etching of nimonic alloys. Sometimes the component enters the chrome plating vat while electrically live.